三硫化二铑
| 三硫化二铑 | |
|---|---|
| |
| IUPAC名 Rhodium(III) sulfide | |
| 别名 | 硫化铑(III) |
| 识别 | |
| CAS号 | 12067-06-0 
|
| PubChem | 54672740 |
| ChemSpider | 23349348 |
| SMILES |
|
| InChI |
|
| EINECS | 235-075-0 |
| 性质 | |
| 化学式 | Rh2S3 |
| 摩尔质量 | 302.01 g·mol−1 |
| 外观 | 黑色固体 |
| 密度 | 6.46 g/cm−3 |
| 溶解性（水） | 难溶 |
| 结构 | |
| 晶体结构 | 正交晶系，Pbcn[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
三硫化二铑是一种无机化合物，化学式为Rh2S3。它可由铑和硫在高温反应制得；[2]也可由十六羰基六铑和硫粉在水[3]或二甲苯[4]中的溶剂热反应制得。
它是一些化合物的晶体结构原型[5]，属于Rh2S3结构的化合物有Rh2Se3、Ir2S3、[2]高压相Sn2N2O[6]等。
参考文献
[编辑]- ^ Akira Yoshiasa, Ginga Kitahara, Makoto Tokuda, Satoko Ishimaru, Shin-ichiro Ono, Kunihisa Terai, Akihiko Nakatsuka, Kazumasa Sugiyama. Single-crystal structure refinements and Debye temperatures of Ir 2 S 3 kashinite and Rh 2 S 3 bowieite. Acta Crystallographica Section C Structural Chemistry. 2022-11-01, 78 (11): 606–611 [2023-03-28]. ISSN 2053-2296. doi:10.1107/S2053229622009603. （原始内容存档于2023-03-28）.
- ^ 2.0 2.1 E. Parthé, E. Hohnke, F. Hulliger. A new structure type with octahedron pairs for Rh 2 S 3 , Rh 2 Se 3 and Ir 2 S 3. Acta Crystallographica. 1967-11-01, 23 (5): 832–840 [2023-03-28]. ISSN 0365-110X. doi:10.1107/S0365110X67003767. （原始内容存档于2022-12-01）.
- ^ Wuxing Zhang, Kazumichi Yanagisawa, Sumio Kamiya, Tatsuo Shou. Phase Controllable Synthesis of Well-Crystallized Rhodium Sulfides by the Hydrothermal Method. Crystal Growth & Design. 2009-08-05, 9 (8): 3765–3770 [2023-03-28]. ISSN 1528-7483. doi:10.1021/cg900454g. （原始内容存档于2023-03-28） （英语）.
- ^ Wu-xing Zhang, Kazumichi Yanagisawa, Sumio Kamiya, Tatsuo Shou. Solvothermal Preparation and Control of Phase Composition of Nanosized Rhodium Sulfide Particles. Chemistry Letters. 2009-03-05, 38 (3): 210–211 [2023-03-28]. ISSN 0366-7022. doi:10.1246/cl.2009.210 （英语）.
- ^ Rh2S3 Structure: A2B3_oP20_60_d_cd. Encyclopedia of Crystallographic Prototypes. [2023-03-28]. （原始内容存档于2023-03-28）.
- ^ Shrikant Bhat, Leonore Wiehl, Shariq Haseen, Peter Kroll, Konstantin Glazyrin, Philipp Gollé‐Leidreiter, Ute Kolb, Robert Farla, Jo‐Chi Tseng, Emanuel Ionescu, Tomoo Katsura, Ralf Riedel. A Novel High‐Pressure Tin Oxynitride Sn 2 N 2 O. Chemistry – A European Journal. 2020-02-17, 26 (10): 2187–2194 [2023-03-28]. ISSN 0947-6539. PMC 7065226
. PMID 31671223. doi:10.1002/chem.201904529 （英语）.
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