叠氮化锶
| 叠氮化锶 | ||
|---|---|---|
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| 英文名 | strontium azide | |
| 识别 | ||
| CAS号 | 19465-89-5 
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| PubChem | 57375454 | |
| SMILES |
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| InChI |
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| InChIKey | PDEROVFZLWBVSG-UHFFFAOYSA-N | |
| 性质 | ||
| 化学式 | Sr(N3)2 | |
| 摩尔质量 | 171.66 g·mol⁻¹ | |
| 外观 | 白色晶体粉末[1] | |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | ||
叠氮化锶是一种无机化合物，化学式为Sr(N3)2。它可由叠氮化氢和氢氧化锶八水合物（或碳酸锶[1]）的反应制得。[2]它在潮湿空气中和二氧化碳反应生成碳酸锶。[3]它在含15-冠-5（[15]crown-5）的溶液中结晶，可以得到Sr([15]crown-5)(N3)2(H2O)。[4]它和五氮化三磷在高温、高压下反应，可以得到亚氨基氮代磷酸锶（SrP3N5NH）。[1]
参考文献
[编辑]- ^ 1.0 1.1 1.2 Sebastian Vogel, Wolfgang Schnick. SrP 3 N 5 NH: A Framework‐Type Imidonitridophosphate Featuring Structure‐Directing Hydrogen Bonds. Chemistry – A European Journal. 2018-09-20, 24 (53): 14275–14281 [2022-10-24]. ISSN 0947-6539. doi:10.1002/chem.201803210 （英语）.
- ^ Glen R. Kowach, N.E. Brese, U.M. Bolle, C.J. Warren, F.J. DiSalvo. An Unusual Metallic Nitride: Sr2NiN2. Journal of Solid State Chemistry. 2000-11, 154 (2): 542–550 [2022-10-24]. doi:10.1006/jssc.2000.8877. （原始内容存档于2018-06-07） （英语）.
- ^ Ficheroulle, Henri; Kovache, Adolphe. Manufacture and testing of the azides of barium and strontium. Memorial des Poudres, 1951. 33: 7-19. ISSN 0369-1535.
- ^ Michael D. Brown, Martin F. Davis, John M. Dyke, Francesco Ferrante, William Levason, J. Steven Ogden, Michael Webster. Synthesis, Structures and DFT Calculations on Alkaline-Earth Metal Azide-Crown Ether Complexes. Chemistry - A European Journal. 2008-03-07, 14 (8): 2615–2624 [2022-10-24]. doi:10.1002/chem.200701502 （英语）.
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