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碳酰叠氮

碳酰叠氮
IUPAC名
Carbonyl diazide
别名 羰基叠氮化物
识别
CAS号 14435-92-8  checkY
PubChem 18772028
ChemSpider 11676745
SMILES
 
  • C(=O)(N=[N+]=[N-])N=[N+]=[N-]
性质
化学式 CO(N
3
)
2
摩尔质量 112.05 g/mol g·mol⁻¹
危险性
主要危害 《全球化学品统一分类和标签制度》(简称“GHS”)中爆炸性物质的标签图案
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

碳酰叠氮是一种对撞击敏感的易爆有机化合物,化学式为CO(N
3
)
2
,它可由三光气和四正丁基叠氮化铵在甲醚乙醚溶液中反应制得。[1]它最初于1894年被报道,之后也陆续有其它制备方法的报道。[2]

参考文献

[编辑]
  1. ^ Nolan, Alex M.; Amberger, Brent K.; Esselman, Brian J.; Thimmakondu, Venkatesan S.; Stanton, John F.; Woods, R. Claude; McMahon, Robert J. Carbonyl Diazide, OC(N3)2: Synthesis, Purification, and IR Spectrum. Inorganic Chemistry. 28 September 2012, 51 (18): 9486–9851 [31 October 2023]. PMID 22928580. doi:10.1021/ic301270b. 
  2. ^ Häring, Andreas P.; Kirsch, Stefan F. Synthesis and Chemistry of Organic Geminal Di- and Triazides. Molecules. 6 November 2015, 20 (11): 20044–20062. PMC 6331879可免费查阅. PMID 26561796. doi:10.3390/molecules201119675可免费查阅. 
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碳酰叠氮
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