叠氮化铋
| 叠氮化铋 | |
|---|---|
| 识别 | |
| CAS号 | 115834-32-7 
|
| 性质 | |
| 化学式 | Bi(N3)3 |
| 外观 | 黄色晶体[1]或浅黄色固体[2] 无色固体（四氢呋喃合物）[3] |
| 熔点 | 154 °C（爆炸） 248 °C（四氢呋喃合物，分解）[3] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
叠氮化铋是一种无机化合物，化学式为Bi(N3)3，对撞击和摩擦敏感[1]。它最早由Thomas M. Klapötke和Axel Schulz于1997年通过碘化铋和叠氮化银在乙腈中的反应制得并由红外表征，产物无法和同时生成的碘化银分离。[4]2010年，Alexander Villinger和Axel Schulz通过三氟化铋和三甲基叠氮硅烷的反应制得了纯净的叠氮化铋。[3]它的多种溶剂合物是已知的。[1]
参考文献
[编辑]- ^ 1.0 1.1 1.2 Rosenstengel, Kati; Schulz, Axel; Villinger, Alexander. Solid State Structure of Bi(N3)3, Bi(N3)3·Solvates and the Structural Dynamics in the [Bi(N3)6]3– Anion. Inorganic Chemistry (American Chemical Society (ACS)). 2013-05-09, 52 (10): 6110–6126. ISSN 0020-1669. doi:10.1021/ic400493v.
- ^ Haiges, Ralf; Rahm, Martin; Dixon, David A.; Garner, Edward B.; Christe, Karl O. Binary Group 15 Polyazides. Structural Characterization of [Bi(N3)4]−, [Bi(N3)5]2–, [bipy·Bi(N3)5]2–, [Bi(N3)6]3–, bipy·As(N3)3, bipy·Sb(N3)3, and [(bipy)2·Bi(N3)3]2 and on the Lone Pair Activation of Valence Electrons. Inorganic Chemistry (American Chemical Society (ACS)). 2011-12-23, 51 (2): 1127–1141. ISSN 0020-1669. doi:10.1021/ic202307a.
- ^ 3.0 3.1 3.2 Villinger, Alexander; Schulz, Axel. Binary Bismuth(III) Azides: Bi(N3)3 , [Bi(N3)4]−, and [Bi(N3)6]3−. Angewandte Chemie International Edition (Wiley). 2010-09-13, 49 (43): 8017–8020. ISSN 1433-7851. doi:10.1002/anie.201002179.
- ^ Klapötke, Thomas M.; Schulz, Axel. GROUP 15 TRIAZIDES: A COMPREHENSIVE THEORETICAL STUDY AND THE PREPARATION OF BISMUTH TRIAZIDE. Main Group Metal Chemistry (Walter de Gruyter GmbH). 1997, 20 (5). ISSN 2191-0219. doi:10.1515/mgmc.1997.20.5.325.
| ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
Text is available under the CC BY-SA 4.0 license; additional terms may apply.
Images, videos and audio are available under their respective licenses.
Cover photo is available under {{::mainImage.info.license.name || 'Unknown'}} license.
Cover photo is available under {{::mainImage.info.license.name || 'Unknown'}} license.
Credit:
(see original file).
