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硫酸银(II)

硫酸银(II)
识别
CAS号 16106-39-1  checkY
性质
化学式 AgSO4
外观 黑色
相关物质
其他阴离子 氟锑酸银(II)
其他阳离子 硫酸铜
硫酸金(II)
相关化学品 硫酸银
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

硫酸银(II)是一种无机化合物,化学式为AgSO4,它最初于2010年被发现[1]。它可由AgII盐在无水氟化氢中的复分解反应制得:[2]

Ag(SbF6)2 + K2SO4 → AgSO4↓ + 2 KSbF6
AgF2 + H2SO4 → AgSO4↓ + 2 HF

它和其它二价银盐一样,热稳定性较低,在110 °C即分解为焦硫酸银和氧气[3]

参考文献

  1. ^ 注释:文章(Przemysław J. Malinowski; et al.)于2009年12月投稿,2010年接收并发表
  2. ^ Przemysław J. Malinowski, Mariana Derzsi, Zoran Mazej, Zvonko Jagličić, Bartłomiej Gaweł, Wiesław Łasocha, Wojciech Grochala. AgIISO4: A Genuine Sulfate of Divalent Silver with Anomalously Strong One-Dimensional Antiferromagnetic Interactions. Angewandte Chemie International Edition. 2010-02-22, 49 (9): 1683–1686 [2022-11-04]. doi:10.1002/anie.200906863. (原始内容存档于2022-11-04) (英语). 
  3. ^ Wojciech Grochala, Zoran Mazej. Chemistry of silver(II): a cornucopia of peculiarities. Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences. 2015-03-13, 373 (2037): 20140179 [2022-11-04]. ISSN 1364-503X. doi:10.1098/rsta.2014.0179. (原始内容存档于2022-09-22) (英语). 
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硫酸银(II)
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