高锝酸银
| 高锝酸银 | ||
|---|---|---|
| ||
| 识别 | ||
| CAS号 | 2490367-31-0  193026-99-2（99Tc）
| |
| 性质 | ||
| 化学式 | AgO4Tc | |
| 摩尔质量 | 268.87 g·mol−1 | |
| 外观 | 黄色固体 | |
| 密度 | 5.398 g·cm−3 | |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | ||
高锝酸银是一种无机化合物，化学式为AgTcO4，它的空间群为I41/a，与AgReO4同构。[1]
它可由高锝酸铵和硝酸银在水中反应得到。[2]它和三甲基氯硅烷反应，得到高锝酸三甲基硅酯。[2]它和[UO2(Cl)(L)2]Cl（L为双(二苯基膦基)甲烷二氧化物）反应，可以得到[UO2(TcO4)(L)2]TcO4。[3]
参考文献
- ^ Mark J. Sarsfield, Andrew D. Sutton, Francis R. Livens, Iain May, Robin J. Taylor. Raman spectroscopy of silver pertechnetate. Acta Crystallographica Section C Crystal Structure Communications. 2003-06-15, 59 (6): i45–i46 [2022-08-29]. ISSN 0108-2701. doi:10.1107/S0108270103006486. （原始内容存档于2022-08-29）.
- ^ 2.0 2.1 William A. Nugent. Synthesis of some d0 organoimido complexes of the early transition metals. Inorganic Chemistry. 1983-03, 22 (6): 965–969 [2022-08-29]. ISSN 0020-1669. doi:10.1021/ic00148a023. （原始内容存档于2022-08-29） （英语）.
- ^ Andrew D. Sutton, Gordon H. John, Mark J. Sarsfield, Joanna C. Renshaw, Iain May, Leigh R. Martin, Andrew J. Selvage, David Collison, Madeleine Helliwell. Spectroscopic Evidence for the Direct Coordination of the Pertechnetate Anion to the Uranyl Cation in [UO 2 (TcO 4 )(DPPMO 2 ) 2 ] +. Inorganic Chemistry. 2004-09-01, 43 (18): 5480–5482 [2022-08-29]. ISSN 0020-1669. doi:10.1021/ic049588r. （原始内容存档于2022-08-29） （英语）.
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