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环三硫酰亚胺三银

环三硫酰亚胺三银
别名 环三硫酰氨基银
识别
CAS号 14284-17-4(无水)  checkY
53962-16-6(三水)  checkY
SMILES
 
  • [Ag].O=S1(=O)NS(=O)(=O)NS(=O)(=O)N1
性质
化学式 Ag3N3O6S3
摩尔质量 557.82 g·mol−1
密度 3.72 g·cm-3(三水)[1]
3.90 g·cm-3(三水)[2]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

环三硫酰亚胺三银是一种无机化合物,化学式为(AgNSO2)3,它是环三硫酰胺的银盐,可由环三硫酰亚胺三铵和银盐的复分解反应制得。[3]它的水合物在110 °C加热,可以得到无水物。它和碘甲烷碘乙烷反应,可以得到相应甲基或乙基环胺衍生物。[3]

参考文献

  1. ^ Andress, K. R.; Fischer, K. Crystal structure of silver sulfimide Ag3(NSO2)3·3H2O. Naturwissenschaften (1953), 40, 240-241. doi:10.1007/BF00591544
  2. ^ Fischer, K.; Andress, K. R. Crystal structure of silver trisulfimide hydrate (AgNSO2.-H2O)3. Zeitschrift fuer Anorganische und Allgemeine Chemie (1955), 281, 169-182. doi:10.1002/zaac.19552810306
  3. ^ 3.0 3.1 Heinze, Gerhard; Meuwsen, Alwin. Trimeric sulfimide, (O2SNH)3. Zeitschrift fuer Anorganische und Allgemeine Chemie (1954), 275, 49-58. doi:10.1002/zaac.19542750105
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环三硫酰亚胺三银
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