氰化亚硝酰
| 氰化亚硝酰 | |
|---|---|
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| 识别 | |
| CAS号 | 4343-68-4 
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| PubChem | 123214 |
| ChemSpider | 109829 |
| SMILES |
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| 性质 | |
| 化学式 | CN2O |
| 摩尔质量 | 56.02 g·mol−1 |
| 外观 | 蓝绿色气体 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
氰化亚硝酰是一种化合物，化学式为ONCN，它是蓝绿色气体。[1]它是葡萄糖氧化酶催化的氨基氰氧化的产物。[2]
制备与结构
[编辑]氰化亚硝酰可由亚硝酰氯和氰化银在低温反应得到，它是平面分子，结构类似于亚硝酰氯。[1]计算表明它可能存在同分异构体。[3]
参考文献
[编辑]- ^ 1.0 1.1 Kirby, G. W. Tilden Lecture. Electrophilic C-nitroso-compounds. Chemical Society Reviews. 1977, 6: 1. doi:10.1039/CS9770600001.
- ^ Shirota, Frances N.; Goon, David J.W.; Demaster, Eugene G.; Nagasawa, Herbert T. Nitrosyl cyanide, a putative metabolic oxidation product of the alcohol-deterrent agent cyanamide. Biochemical Pharmacology. 1996, 52 (1): 141–147. PMID 8678898. doi:10.1016/0006-2952(96)00174-8.
- ^ Günther Maier, Hans Peter Reisenauer, Jürgen Eckwert, Matthias Naumann, Michael De Marco. Isomers of the Elemental Composition CN2O. Angewandte Chemie International Edition in English. 1997-09-01, 36 (16): 1707–1709 [2020-07-17]. ISSN 0570-0833. doi:10.1002/anie.199717071 （英语）.
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