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高碘酸银

高碘酸银

识别
CAS号 15606-77-6  checkY
性质
化学式 AgIO4
摩尔质量 298.77 g·mol−1
外观 亮黄色粉末(无水)
橙色晶体(一水)
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

高碘酸银是一种无机化合物,化学式为AgIO4,它是高碘酸盐之一。它的一水合物可由原高碘酸盐Ag2H3IO6硝酸反应得到,加热脱水得到无水物。[1]高碘酸钾硫酸银在浓硫酸中反应,或和高氯酸银在浓硝酸中反应,也能得到无水高碘酸银。[2]

它的I NMR碘化学位移为αiso +0.541(5)%、αax −0.033(10)%。[3]

参考文献

[编辑]
  1. ^ C. W. Kimmins. XXXIV—Contributions from the Laboratory of Gonville and Caius College, Cambridge. No. IX. Periodates. J. Chem. Soc., Trans. 1887, 51 (0): 356–361 [2022-09-29]. ISSN 0368-1645. doi:10.1039/CT8875100356 (英语). 
  2. ^ Birckenbach, L.; Buschendorf, F. Preparation and crystal structure of normal (meta) silver periodate. Z. physik. Chem., 1932. B16. 102-112.
  3. ^ S. L. Segel, H. M. Vyas. Iodine chemical shifts in alkali metal metaperiodates and iodates. The Journal of Chemical Physics. 1980-01-15, 72 (2): 1406–1407 [2022-09-29]. ISSN 0021-9606. doi:10.1063/1.439220. (原始内容存档于2022-10-07) (英语). 
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高碘酸银
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