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钨酸钾

钨酸钾
识别
CAS号 7790-60-5
PubChem 3084032
SMILES
 
  • [K+].[K+].[O-][W](=O)(=O)[O-]
EC编号 232-215-2
性质
化学式 K2O4W
摩尔质量 326.03 g·mol−1
外观 无色无臭固体[1]
密度 3.12 g·cm−3(25 °C)[2]
溶解性 可溶于水[3]
溶解性 不溶于乙醇[3]
结构[4]
晶体结构 单斜晶系
空间群 C2/m(No. 12)
晶格常数 a = 12.39 Å, b = 6.105 Å, c = 7.560 Å
晶格常数 α = 90°, β = 115.96°, γ = 90°
危险性[1]
GHS危险性符号
《全球化学品统一分类和标签制度》(简称“GHS”)中有害物质的标签图案
H-术语 H319, H335
P-术语 P261, P280, P305+351+338, P304+340, P405, P501
相关物质
其他阴离子 硫酸钾
铬酸钾
钼酸钾
其他阳离子 钨酸锂
钨酸钠
钨酸铷俄语Вольфрамат рубидия
钨酸铯
相关化学品 重钨酸钾
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

钨酸钾的一种钨酸盐,化学式K2WO4。钾的其它钨酸盐包括K0.33WO3.165重钨酸钾K2W2O7[5][6]

制备

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钨酸钾可由钨酸钙氟化钾反应得到:[7]

它也可由钨酸焦硫酸钾的反应产生:[8]

性质

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钨酸钾是无色无臭固体,[1]可溶于水。它存在二水合物。[3]在常温常压下,钨酸钾是单斜晶系的晶体,空间群C2/m(No. 12)。[4]钨酸钾在375 °C和455 °C时都会发生相变,后者会产生六方晶系,空间群P63/mmc(No. 194)的晶体。钨酸钾在高压下也会相变,产生另一种单斜晶系晶体。[9]

参考资料

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  1. ^ 1.0 1.1 1.2 Datenblatt Potassium tungsten oxide, 99.5% (metals basis) bei AlfaAesar, abgerufen am 2016-06-06.
  2. ^ 来源:Sigma-Aldrich Co., product no. 372617 .
  3. ^ 3.0 3.1 3.2 Perry, Dale L. Handbook of Inorganic Compounds. CRC Press. 2016-04-19. ISBN 978-1-4398-1462-8. 
  4. ^ 4.0 4.1 Koster, A. S.; Kools, F. X. N. M.; Rieck, G. D. The crystal structure of potassium tungstate, K 2 WO 4. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry. 1969-09-01, 25 (9): 1704–1708. ISSN 0567-7408. doi:10.1107/S0567740869004602. 
  5. ^ Wagata, Hajime; Fujisawa, Maki; Mizuno, Yusuke; Zettsu, Nobuyuki; Oishi, Shuji; Teshima, Katsuya. Fabrication of Combined One-Dimensional and Three-Dimensional Structure of Potassium Tungstate Crystal Layers by Spray Deposition with Polystyrene Colloidal Crystal Templates. Crystal Growth & Design. 2013-08-07, 13 (8): 3294–3298. ISSN 1528-7483. doi:10.1021/cg400714e. 
  6. ^ Range, Klaus-Jürgen; Hegenbart, Wilhelm; Heyns, Anton M.; Rau, Franz; Klement, Ulrich. Hochdrucksynthese und Kristallstruktur von Kalium- und Rubidiumdiwolframat(VI), K2W2O7 und Rb2W2O7 / High-Pressure Synthesis and Crystal Structure of Potassium and Rubidium Ditungstate(VI), K2W2O7 und Rb2W2O7. Zeitschrift für Naturforschung B. 1990-02-01, 45 (2): 107–110. ISSN 1865-7117. doi:10.1515/znb-1990-0202. 
  7. ^ Advanced Inorganic Chemistry Vol-1. Krishna Prakashan Media. 2008: 1215. ISBN 978-81-87224-03-7. 
  8. ^ Vorproben und Trennungen der Kationen und Anionen: Analyse durch Vorproben Lösen und Aufschliessen Trennungsgänge. Springer-Verlag. 2013: 97. ISBN 978-3-662-30604-8. 
  9. ^ Tonkov, E. Yu. High Pressure Phase Transformations Handbook 3. Philadelphia: CRC Press. 1996-04-01: 129. ISBN 2-88449-017-5. 
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钨酸钾
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