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高氯酸锌

高氯酸锌
英文名 Zinc perchlorate
识别
CAS号 13637-61-1  checkY[SciFinder][2]
10025-64-6(六水)  checkY[chemicalbook][3]
PubChem 10199167
ChemSpider 8374666
SMILES
 
  • [O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[Zn+2][1]
InChI
 
  • InChI=1S/2ClHO4.Zn/c2*2-1(3,4)5;/h2*(H,2,3,4,5);/q;;+2/p-2[1]
InChIKey RXBXBWBHKPGHIB-UHFFFAOYSA-L[1]
EC编号 237-122-0
RTECS SD0525000[3]
性质
化学式 Zn(ClO4)2
摩尔质量 264.310[1] g·mol⁻¹
密度 2.252[3]g·cm-3
熔点 106℃[3]
沸点 210℃[3]
溶解性 溶于水、酒精[3]
折光度n
D
1.50[3]
危险性
欧盟危险性符号
氧化性氧化性 O
腐蚀性腐蚀性 C
[3]
警示术语 R:R8R34[3]
安全术语 S:S17S26S27S36/37/39S45[3]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

高氯酸锌(英语:Zinc perchlorate)是高氯酸盐,其分子式为Zn(ClO4)2

化学性质

高氯酸铜高氯酸铅等大部分其他高氯酸盐一样,高氯酸锌容易潮解[3]

高氯酸锌可以和8-氨基喹啉[4]、三碳酰肼[5]、四苯乙烯四三唑[6]等配体形成配合物。

应用

尿素1,2-丙二醇运用尿素醇解法合成碳酸丙烯酯过程中,高氯酸锌可以作为催化剂,且效果比乙酸锌氯化锌、碱式碳酸锌等其他锌盐要好[7]。高氯酸锌可使幼小动物增重并节省饲料,提高产量,还可以预防鱼类的出血性败血症,防控家禽感染禽流感[8]

参考资料

  1. ^ 1.0 1.1 1.2 1.3 Zinc perchlorate | Cl2O8Zn | ChemSpider. ChemSpider. [2017-08-12] (英语). 
  2. ^ Retrieved from SciFinder. [2017.11.4]
  3. ^ 3.00 3.01 3.02 3.03 3.04 3.05 3.06 3.07 3.08 3.09 3.10 高氯酸锌 | 10025-64-6. www.chemicalbook.com. [2017-08-12]. 
  4. ^ 徐衡, 冯学军, 赵顺平,等. 8-氨基喹啉高氯酸锌金属配合物及其制备方法与应用:, CN103755633A[P]. 2014.
  5. ^ 孙远华, 张同来, 张建国,等. 高氯酸三碳酰肼合锌([Zn(CHZ)3](ClO4)2)的T-jump/FTIR快速热分解研究[J]. 火工品, 2005(3):18-21.
  6. ^ 王英. 具有潜在荧光材料的四苯乙烯四三唑高氯酸锌配合物及其制备方法:, CN 104628749 A[P]. 2015.
  7. ^ 丁明; 赵宁钰; 朱伟光; 刘定华; 刘晓勤. 高氯酸锌催化尿素与1,2-丙二醇合成碳酸丙烯酯. 精细化工. 2014, 31 (09): 1169–1172 [2022-04-19]. ISSN 1003-5214. doi:10.13550/j.jxhg.2014.09.155. (原始内容存档于2022-04-19). 
  8. ^ 姜礼燔; 许云萍; 王乙力. 复合高氯酸锰锌在水产禽畜养殖中抗病促长作用研究. 广东饲料. 2013, 22 (08): 42–43 [2022-04-19]. ISSN 1005-8613. (原始内容存档于2022-04-19). 
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高氯酸锌
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