二异丙基锌
| 二异丙基锌 | |
|---|---|
| |
| |
| 识别 | |
| CAS号 | 625-81-0 
|
| PubChem | 5207587 |
| ChemSpider | 11347073 |
| SMILES |
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| InChI |
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| InChIKey | KDUNMLRPPVCIGP-LSPCJBSIAV |
| 性质 | |
| 化学式 | C6H14Zn |
| 摩尔质量 | 151.56 g·mol⁻¹ |
| 沸点 | 300 °C（573 K）（分解）[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
二异丙基锌 是一种有机锌化合物 ，化学式 ZnC6H14。[2]它可由锌粉和2-碘丙烷在200 °C反应制得；[1]或者由2-溴丙烷和镁反应制得格氏试剂异丙基溴化镁，再在乙醚中和溴化锌反应得到。[3]
它是Soai反应中的关键试剂，它既具有自催化性又具有对映体特异性。 [4]
参考资料
[编辑]- ^ 1.0 1.1 Pochekutova, T. S.; Khamylov, V. K.; Domrachev, G. A.; Zhuk, B. V. Direct synthesis of dipropyl- and diisopropylzinc. Zhurnal Organicheskoi Khimii, 1987. 23 (10): 2156-2160. ISSN: 0514-7492.
- ^ Benjamin Bederson; Herbert Walther. Advances in Atomic, Molecular, and Optical Physics. Gulf Professional Publishing. 2002: 250– [2013-08-06]. ISBN 978-0-12-003848-0. （原始内容存档于2016-05-09）.
- ^ Eike Hupe, M. Isabel Calaza, Paul Knochel. Substrate-Controlled Highly Diastereoselective Synthesis of Primary and Secondary Diorganozinc Reagents by a Hydroboration/Boron–Zinc Exchange Sequence. Chemistry - A European Journal. 2003-06-16, 9 (12): 2789–2796 [2020-12-07]. doi:10.1002/chem.200204662.
- ^ Shibata, Takanori; Morioka, Hiroshi; Hayase, Tadakatsu; Choji, Kaori; Soai, Kenso. Highly Enantioselective Catalytic Asymmetric Automultiplication of Chiral Pyrimidyl Alcohol. Journal of the American Chemical Society. 1996, 118: 471. doi:10.1021/ja953066g.
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