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高氯酸氧锆

高氯酸氧锆

英文名 Zirconyl perchlorate
别名 高氯酸锆酰
识别
CAS号 15607-09-7  checkY
性质
化学式 ZrO(ClO4)2
摩尔质量 306.130(无水)
342.162(二水)
450.258(八水) g·mol⁻¹
外观 无色片状晶体[1]
相关物质
其他阴离子 硝酸氧锆
氧氯化锆
其他阳离子 高氯酸氧钛
高氯酸氧铪
相关化学品 高氯酸锆
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

高氯酸氧锆是一种无机化合物,化学式为ZrO(ClO4)2,易溶于,溶于水放热,在水中解离出ZrO2+和ClO4离子

制备

[编辑]

先从其它锆盐沉淀得到氢氧化锆,用蒸馏水洗涤,加入化学计量比高氯酸反应,通过吹过干燥空气使溶液在室温挥发,得到ZrO(ClO4)2·8H2O晶体。[1]

Zr(OH)4 + 2 HClO4 + 5 H2O → ZrO(ClO4)2·8H2O

参考文献

[编辑]
  1. ^ 1.0 1.1 Murthy, P. Rama; Patel, C. C. Zirconyl perchlorate. Naturwissenschaften, 1961. Vol 48. pp 693. DOI:10.1007/BF00595937

拓展阅读

[编辑]
  • Venable, F. P.; Smithey, I. W. Zirconyl compounds with the oxy-halogen acids. Journal of the American Chemical Society, 1919. 41: 1722-7. DOI: 10.1021/ja02232a004
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高氯酸氧锆
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