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二磷烯

二磷烯
识别
CAS号 41916-72-7  checkY
PubChem 142559
ChemSpider 125761
SMILES
 
  • P=P
性质
化学式 P
2
H
2
摩尔质量 63.96340 g·mol⁻¹
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

二磷烯又称乙磷烯,是一种氢化物化学式为(PH)2。它存在E型和Z型的顺反异构[1]。二磷烯也是二膦烯英语Diphosphenes类化合物的母体,它们的通式为(PR)2,其中R代表一个有机基团[2]

参考资料

  1. ^ Lu, Tongxiang; Simmonett, Andrew C.; Evangelista, Francesco A.; Yamaguchi, Yukio; Schaefer, Henry F. Diphosphene and Diphosphinylidene. The Journal of Physical Chemistry A. 26 November 2009, 113 (47): 13227–13236. doi:10.1021/jp904028a. 
  2. ^ Yoshifuji, Masaaki; Shibayama, Katsuhiro; Inamoto, Naoki; Hirotsu, Ken; Higuchi, Taiichi. Reaction of the diphosphene ArP=PAr (Ar = 2,4,6-But3C6H2) with sulphur: isolation and X-ray structure of the diphosphene monosulphide. Journal of the Chemical Society, Chemical Communications. 1 January 1983, (16): 862. doi:10.1039/C39830000862. 
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二磷烯
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