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二氢化钕

二氢化钕
英文名 Neodymium dihydride
识别
CAS号 13863-22-4  checkY
性质
化学式 NdH2
相关物质
相关化学品 三氢化钕
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

二氢化钕是一种无机化合物,化学式为NdH2,它以Nd3+(e)(H)2的形式存在。NdH2具有铁磁性[1]

化学性质

二氢化钕和硼氢化锂反应,可以得到四硼化钕:[2]

NdH2 + 4 LiBH4 → NdB4 + 4 LiH + 7 H2

参考文献

  1. ^ 洪广言. 现代化学基础丛书 第36卷 稀土化学导论. 北京: 科学出版社, 2014. pp. 57-59. 3.2.4 稀土氢化物 ISBN 978-7-03-040581-4
  2. ^ Cai, Weitong; Wang, Hui; Sun, Dalin; Zhu, Min. Nanosize-controlled reversibility for a destabilizing reaction in the LiBH4-NdH2+x system. Journal of Physical Chemistry C, 2013. 117(19): 9566-9572. DOI:10.1021/jp402332q

参见

拓展阅读

  • Struss, Arthur W.; Corbett, John D. Reaction of hydrogen with metallic and reduced halides. The requirement of delocalized electrons for reaction. Inorganic Chemistry, 1978. 17(4): 965-9. DOI:10.1021/ic50182a034
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二氢化钕
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