亚苄基丙酮三羰基铁
| 亚苄基丙酮三羰基铁 | |
|---|---|
iron-tricarbonyl-2D-skeletal.png)
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Fe(CO)3-from-xtal-Mercury-3D-bs1.png)
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Fe(CO)3-Crystals.jpg)
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| 识别 | |
| CAS号 | 38333-35-6 
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| PubChem | 11403415 |
| ChemSpider | 9578311 |
| SMILES |
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| 性质 | |
| 化学式 | C13H10FeO4 |
| 摩尔质量 | 286.060 g·mol⁻¹ |
| 外观 | 红色固体 |
| 熔点 | 88—89 °C（361—362 K） |
| 溶解性（水） | 微溶 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
亚苄基丙酮三羰基铁是一种有机铁化合物，化学式为(C6H5CH=CHC(O)CH3)Fe(CO)3，可简写为(bda)Fe(CO)3，这种红色固体是Fe(CO)3单元的转移试剂。[1]
它可由Fe2(CO)9和亚苄基丙酮反应制得。[2]它可以和路易斯碱形成加合物，反应过程中bda配体不会被取代。[3]
参考文献
[编辑]- ^ Knölker, H.-J. "(η4-Benzylideneacetone)tricarbonyliron" in Encyclopedia of Reagents for Organic Synthesis (Ed: L. Paquette) 2004, J. Wiley & Sons, New York. doi:10.1002/047084289X.
- ^ Domingos, A. J. P.; Howell, J. A. S.; Johnson, B. F. G.; Lewis, J. Reagents for the Synthesis of η-Diene Complexes of Tricarbonnyliron and Tricarbonylruthenium. Inorg. Synth. 1990, 28: 52–55. doi:10.1002/9780470132593.ch11.
- ^ Howell, J. A. S.; Kola, J. C.; Dixon, D. T.; Burkinshaw, P. M.; Thomas, M. J. The kinetics and mechanism of diene exchange in (η4-enone)Fe(CO)2L complexes (L = phosphine, phosphite). Journal of Organometallic Chemistry. 1984, 266: 83–96. doi:10.1016/0022-328X(84)80113-8.
延伸阅读
[编辑]- Alcock, N. W.; Richards, C. J.; Thomas, S. E. Preparation of Tricarbonyl(η4-vinylketene)iron(0) Complexes from Tricarbonyl(ε4-vinyl ketone)iron(0) Complexes and Their Subsequent Conversion to Tricarbonyl(ε4-vinylketenimine)iron(0) Complexes. Organometallics. 1991, 10: 231–238. doi:10.1021/om00047a054.
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