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四亚硝基合铁

四亚硝基合铁
IUPAC名
四亚硝基合铁(0)
英文名 Tetranitrosyliron
别名 四亚硝酰铁
识别
CAS号 99904-52-6  checkY
性质
化学式 Fe(NO)4
摩尔质量 175.873 g·mol⁻¹
外观 黑色晶体[1]
相关物质
相关化学品 五羰基铁
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

四亚硝基合铁是一种无机配位化合物,化学式为Fe(NO)4,不挥发,反应活性高。

制备

[编辑]

四亚硝基合铁可由五羰基铁一氧化氮在压热釜中加热至45℃反应得到。[1]

化学性质

[编辑]

四亚硝基合铁在空气中易被氧化。

可以和氰化钠反应得到亚硝基铁氰化钠

参考资料

[编辑]
  1. ^ 1.0 1.1 《无机化学丛书》.第九卷 锰分族 铁系 铂系. 科学出版社. P163. 四亚硝基合铁 Fe(NO)4
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四亚硝基合铁
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