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硫氰酸钯.
硫氰酸钯是一种无机化合物，化学式为Pd(SCN)2。
制备
硫氰酸钯可由硝酸钯或氯化钯和硫氰酸铵溶液反应得到。[1][2]加热Pd(NCS)2(PnBu3)2至290℃也能得到硫氰酸钯。[3]
性质
硫氰酸钯和硫氰酸盐作用，产生[Pd(SCN)4]2-，和吡啶作用，得到Pd(SCN)2(py)2。[1]
用途
由于硫氰酸钯的难溶性，可被用于Pd的分析。[2]
参考文献
- ^ 1.0 1.1 Golub, A. M.; Pomerants, G. B. (Zh. Neorgan. Khim. 9 [1964]1624/9; Russ. J. Inorg. Chem. 9 [1964] 879/82).
- ^ 2.0 2.1 Przheval'skii, E. S.; Shlenskaya, V. I. (Vestn. Mosk. Univ. 7 No. 5 [1952] Ser. Fiz. Mat. Estestv. Nauk. No. 3 61/7; C.A. 1953 4789).
- ^ Pinna, R.; Ponticelli, G.; Preti, C. J. lnorg. Nucl. Chem. 37 [1975] 1681/4
拓展阅读
- Chemistry of Pseudohalides, Elsevier, Amsterdam 1986
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| | 卤素化合物 | |
|---|
| | 氧族化合物 |
- PdO
- Pd(OH)2
- PdO2
- Pd(OH)4
- Pd4S
- Pd2S
- PdS
- PdS2
- PdSO4
- Pd(SO3F)2
- Pd(SO3F)3
- Pd(SCN)2
- Pd(SCN)(OH)
- Pd4Se
- PdSe
- PdSe2
- PdSSe
- PdSeO4
- Pd4Te
- PdTe
- PdTe2
- PdSeTe
- PdSbTe
- PdBiTe
|
|---|
| | 氮族化合物 | |
|---|
| | 碳族元素 | |
|---|
| | 钯酸盐 |
- Cs[PdF3]
- [XeF][PdF5]
- (NO)2[PdF6]
- K2[PdF6]
- Cs2[PdF6]
- O2[PdF6]
- H2[PdCl4]
- Na2[PdCl4]
- K2[PdCl4]
- (NH4)2[PdCl4]
- Ba[PdCl4]
- [(CH3)4N]2[PdCl4]
- [Ph4P]2[PdCl4]
- H2[PdCl6]
- K2[PdCl6]
- (NH4)2[PdCl6]
- K2[PdBr4]
- K2[PdBr6]
- K2[PdI4]
- Li2PdO2
- Na2PdO2
- La2Pd2O5
- CoPdO2
- Li2PdO3
- Na2[Pd(OH)4]
- K2[Pd(OH)4]
- Na2[Pd(OH)6]
- Ca[Pd(OH)6]
- Na2PdS2
- K2Pd3S4
- Na2[Pd(SH)4]
- [(C2H5)4N]2[Pd(WS4)2]
- Na2[Pd(SO3)2]
- Na6[Pd(SO3)4]
- K2[Pd(S2O3)2]
- K2Pd3Se4
- K2[Pd(NO3)4]
- K2PdP2
- K4[Pd(CN)4]
- H2[Pd(CN)4]
- Na2[Pd(CN)4]
- K2[Pd(CN)4]
- [(C2H5)4N]2[Pd(CN)4]
- Ba[Pd(CN)4]
- K2[Pd(CN)6]
- Co[Pd(CN)6]
- Ni[Pd(CN)6]
- [(C2H5)4N]2[Pd(SCN)4]
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| | 其它无机钯化合物 | |
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| | 有机钯化合物 | |
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