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[1,1'-双(二苯基膦)二茂铁]二氯化钯

[1,1'-双(二苯基膦)二茂铁]二氯化钯
识别
CAS号 72287-26-4  checkY
95464-05-4DCM络合物)  checkY
ChemSpider 24602493
性质
化学式 C34H28Cl2FeP2Pd
摩尔质量 731.7 g·mol−1
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

[1,1'-双(二苯基膦)二茂铁]二氯化钯(II)是一种含配体——dppf络合物。这是一种商业市售试剂,常用于钯催化偶联反应

这种化合物可通过dppf与络合的氯化钯反应制备:[1]

dppf + PdCl2(RCN)2 → (dppf)PdCl2 + 2 RCN (RCN = 乙腈苯甲腈)

参考文献

  1. ^ Nataro, Chip; Fosbenner, Stephanie M. Synthesis and Characterization of Transition-Metal Complexes Containing 1,1’-Bis(diphenylphosphino)ferrocene. J. Chem. Ed. 2009, 86: 1412. doi:10.1021/ed086p1412. 
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[1,1'-双(二苯基膦)二茂铁]二氯化钯
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