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焦磷酸钯.
焦磷酸钯是一种无机化合物,化学式为Pd2P2O7。
制备
氧化钯(II)和磷酸于150℃反应,得到暗棕色固体,将其在空气中加热至500℃,得到Pd2P2O7粉末。[2]
化学性质
焦磷酸钯具有很高的热稳定性,在950℃以上按下式分解:[2]
- 2 Pd2P2O7 → 4 Pd + P4O10 + 2 O2↑
复盐
焦磷酸钯可以形成复盐,如Li2PdP2O7、Na2PdP2O7[1]、Ag2PdP2O7[3]等。
参考文献
- ^ 1.0 1.1 K. Panagiotidis, et al. Beiträge zur Kristallchemie und zum thermischen Verhalten von wasserfreien Phosphaten. XXXVI [1] Synthese, Kristallstruktur und spektroskopische Charakterisierung von Palladium(II)-diphosphat Pd2P2O7. ZAAC, 2005. doi: 10.1002/zaac.200500208
- ^ 2.0 2.1 K. PANAGIOTIDIS et al. Pd2P2O7 AND AuPO4 - NEW ANHYDROUS PHOSPHATES OF NOBLE METALS. Phosphorus Research Bulletin Vol. 19 (2005) p. 77-82. doi: 10.3363/prb1992.19.0_77
- ^ Kosta Panagiotidis and Robert Glaum. Ag2PdP2O7. Acta Crystallogr Sect E Struct, 2008. 64(Pt12): i184
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| 卤素化合物 | |
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| 氧族化合物 |
- PdO
- Pd(OH)2
- PdO2
- Pd(OH)4
- Pd4S
- Pd2S
- PdS
- PdS2
- PdSO4
- Pd(SO3F)2
- Pd(SO3F)3
- Pd(SCN)2
- Pd(SCN)(OH)
- Pd4Se
- PdSe
- PdSe2
- PdSSe
- PdSeO4
- Pd4Te
- PdTe
- PdTe2
- PdSeTe
- PdSbTe
- PdBiTe
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| 氮族化合物 | |
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| 碳族元素 | |
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| 钯酸盐 |
- Cs[PdF3]
- [XeF][PdF5]
- (NO)2[PdF6]
- K2[PdF6]
- Cs2[PdF6]
- O2[PdF6]
- H2[PdCl4]
- Na2[PdCl4]
- K2[PdCl4]
- (NH4)2[PdCl4]
- Ba[PdCl4]
- [(CH3)4N]2[PdCl4]
- [Ph4P]2[PdCl4]
- H2[PdCl6]
- K2[PdCl6]
- (NH4)2[PdCl6]
- K2[PdBr4]
- K2[PdBr6]
- K2[PdI4]
- Li2PdO2
- Na2PdO2
- La2Pd2O5
- CoPdO2
- Li2PdO3
- Na2[Pd(OH)4]
- K2[Pd(OH)4]
- Na2[Pd(OH)6]
- Ca[Pd(OH)6]
- Na2PdS2
- K2Pd3S4
- Na2[Pd(SH)4]
- [(C2H5)4N]2[Pd(WS4)2]
- Na2[Pd(SO3)2]
- Na6[Pd(SO3)4]
- K2[Pd(S2O3)2]
- K2Pd3Se4
- K2[Pd(NO3)4]
- K2PdP2
- K4[Pd(CN)4]
- H2[Pd(CN)4]
- Na2[Pd(CN)4]
- K2[Pd(CN)4]
- [(C2H5)4N]2[Pd(CN)4]
- Ba[Pd(CN)4]
- K2[Pd(CN)6]
- Co[Pd(CN)6]
- Ni[Pd(CN)6]
- [(C2H5)4N]2[Pd(SCN)4]
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| 其它无机钯化合物 | |
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| 有机钯化合物 | |
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