甲酸铟
| 甲酸铟 | ||
|---|---|---|
| ||
| 英文名 | indium(III) formate | |
| 识别 | ||
| CAS号 | 40521-21-9 
| |
| 性质 | ||
| 化学式 | In(HCOO)3 | |
| 摩尔质量 | 249.87 g·mol⁻¹ | |
| 外观 | 无色晶体 | |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | ||
甲酸铟是铟和甲酸根离子形成的盐之一，化学式为In(HCOO)3。它存在正盐以及In2(HCOO)5(OH)、In(HCOO)2(OH)等多种碱式盐。[1]
制备
甲酸铟可由氧化铟、甲酸钠和甲酸在155 °C溶剂热反应条件中反应得到。[1]它也可由碳酸铟或硝酸铟和甲酸反应得到。[2]
结构及性质
甲酸铟是六方晶系晶体，空间群P63。[1]甲酸铟和磷化氢在120 °C迅速反应，生成磷化铟。[3]
甲酸铟和吡啶的加合物不稳定。[4]
参考文献
- ^ 1.0 1.1 1.2 Jie Su, Yingxia Wang, Sihai Yang, Guobao Li, Fuhui Liao, Jianhua Lin. New Series of Indium Formates: Hydrothermal Synthesis, Structure and Coordination Modes. Inorganic Chemistry. 2007-10, 46 (20): 8403–8409 [2020-03-23]. ISSN 0020-1669. doi:10.1021/ic7007599 （英语）.
- ^ 田运齐. 无水六方甲酸铟及制备方法. 2007. CN101033185 (A)
- ^ Rostislav D. Preparation of indium phosphide: U.S. Patent 3,010,792. 1961-11-28. (PDF （页面存档备份，存于互联网档案馆）) [2020-03-23]
- ^ Maria T. Andras, Aloysius F. Hepp, Stan A. Duraj, Eric B. Clark, Daniel A. Scheiman, Phillip E. Fanwick, David G. Hehemann. Synthesis, characterization, and decomposition of the first mononuclear eight-coordinate indium(III) benzoate, In(.eta.2-O2CC6H5)3(4-Mepy)2. Inorganic Chemistry. 1993-09, 32 (19): 4150–4152 [2020-03-23]. ISSN 0020-1669. doi:10.1021/ic00071a030 （英语）.
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