一磷化钴
| 一磷化钴 | |
|---|---|
| 别名 | 磷化钴 |
| 识别 | |
| CAS号 | 12052-37-8 
|
| SMILES |
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| 性质 | |
| 化学式 | CoP |
| 摩尔质量 | 89.91 g/mol g·mol⁻¹ |
| 外观 | 灰色晶体[1] |
| 密度 | 6.24 |
| 溶解性（水） | 难溶 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
制备
一磷化钴的制备如下：将1-十八烯（1-octadecylen，ODE）和油胺（OLAM）中的Co2(CO)8热分解，得到ε-Co纳米粉末，再在同样介质中和三辛基膦（TOP）于320℃反应得到。[2]
- Co + P → CoP
用途
参考文献
- ^ 1.0 1.1 姚守拙, 朱元保, 何双娥 等. 元素化学反应手册. 湖南教育出版社, 1998. pp 394
- ^ Eric J. Popczun, Carlos G. Read, Christopher W. Roske, et al. Highly Active Electrocatalysis of the Hydrogen Evolution Reaction by Cobalt Phosphide Nanoparticles[J]. Angewandte Chemie, 2014.
- ^ ST Oyama. Novel catalysts for advanced hydroprocessing: transition metal phosphides[J]. Journal of Catalysis, 2003. 216: 343-352
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