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二苯基汞

二苯基汞
IUPAC名
二苯基汞
识别
CAS号 587-85-9  checkY
PubChem 11488
ChemSpider 11004
SMILES
 
  • c1ccc(cc1)[Hg]c2ccccc2
InChI
 
  • 1/2C6H5.Hg/c2*1-2-4-6-5-3-1;/h2*1-5H;/rC12H10Hg/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12/h1-10H
InChIKey HWMTUNCVVYPZHZ-CYESTLPZAK
EINECS 209-606-1
性质
化学式 C12H10Hg
摩尔质量 354.80 g·mol⁻¹
密度 2.318 g cm−3[1]
沸点 204 °C[1]
溶解性 微溶于乙醇乙醚;可溶于氯仿[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

二苯基汞为一种无色的结晶,[2] 是一种有机汞试剂具有化学式 C12H10Hg。它可以在乙醇中通过摩尔比数2:1二氯化汞和三苯甲基锡制备。[2] 几乎所有的有机汞试剂的配位几何在汞原子上都是线性的。[2]

参考文献

  1. ^ 1.0 1.1 1.2 Lide, David R. CRC Handbook of Chemistry and Physics, 89th Edition. CRC Press. 2008: 3–518. ISBN 978-0849304880. 
  2. ^ 2.0 2.1 2.2 C. Glidewell, J. N. Low, J. L. Wardell. Diphenylmercury, redetermined at 120 K: sheets built from a single C-H…π(arene) hydrogen bond. Acta Cryst. 2005, C61 (Pt 2): m107–m108. PMID 15695887. doi:10.1107/S0108270104034134. 
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二苯基汞
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