氯化氨基汞
| 氯化氨基汞 | |
|---|---|
| |
| IUPAC名 mercuric azanide chloride | |
| 别名 | mercuric amidochloride mercury(II) amide chloride mercury(II) amidochloride ammoniated mercury |
| 识别 | |
| CAS号 | 10124-48-8 
|
| PubChem | 3032553 |
| ChemSpider | 21106343 |
| SMILES |
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| InChI |
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| InChIKey | WRWRKDRWMURIBI-CUFRCDTJAQ |
| 性质 | |
| 化学式 | ClH2HgN |
| 摩尔质量 | 252.065 g·mol⁻¹ |
| 密度 | 5.56 g/cm3 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
氯化氨基汞是一种无机化合物，俗称白降汞，化学式为HgNH2Cl。它由折线型的链状聚合物(HgNH2)n和起着平衡电荷作用的氯离子构成[1][2]。它可以由氨与氯化汞反应制得。此外氨还能将它转化成米隆碱（Millon's base），后者的化学式为[Hg2N]OH(H2O)x。与氯离子、溴离子、氢氧根例子形成的相关的氨基和次氨基化合物都是已知的[3]。
参考资料
[编辑]- ^ Wells, A.F. (1984) Structural Inorganic Chemistry, Oxford: Clarendon Press. ISBN 0-19-855370-6.
- ^ W. N. Lipscomb " The structure of mercuric amidochloride, HgNH2Cl" Acta Crystallographica 1951, volume 4, pp. 266-268. doi:10.1107/S0365110X51000866
- ^ Holleman, A. F.; Wiberg, E. "Inorganic Chemistry" Academic Press: San Diego, 2001. ISBN 0-12-352651-5.
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