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三氟乙酸亚铜

三氟乙酸亚铜
英文名 Copper(I) trifluoroacetate
Cuprous trifluoroacetate
识别
CAS号 25535-55-1 SciFinder
性质
化学式 CF3COOCu
摩尔质量 176.562 g·mol⁻¹
外观 无色潮解性晶体
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

三氟乙酸亚铜是一价铜的三氟乙酸盐,化学式为CF3COOCu。

制备

三氟乙酸亚铜可由氧化亚铜三氟乙酸酐在干燥的中于60-70℃反应,得到苯加合物。将苯加合物在真空中加热至110-120℃升华,得到纯品。[1]

加合物

三氟乙酸亚铜可以形成若干加合物,如Cu4(CF3COO)4(C6H6)2[2]、Cu4(CF3COO)4(EtC≡CEt)2[3]等。

参考文献

  1. ^ Cotton FA , Dikarev EV , Petrukhina MA. Syntheses and crystal structures of "unligated" copper(I) and copper(II) trifluoroacetates. Inorganic Chemistry, 2000. 39(26):6072-6079. DOI: 10.1021/ic000663h
  2. ^ Rodesiler, P. F.; Amma, E. L. J. Chem. Soc. Chem. Commun. 1974, 599.
  3. ^ Reger, D. L.; Huff, M. F.; Wolfe, T. A.; Adams, R. D. Organometallics 1989, 8, 848
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三氟乙酸亚铜
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