三氟乙酸铊
| 三氟乙酸铊 | |
|---|---|
| 别名 | 三氟乙酸铊(III) |
| 识别 | |
| CAS号 | 23586-53-0 
|
| 性质 | |
| 化学式 | C6F9O6Tl |
| 摩尔质量 | 543.43 g·mol−1 |
| 外观 | 白色固体 |
| 熔点 | 100 °C（分解） |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
三氟乙酸铊是一种有机酸盐，化学式为Tl(OCOCF3)3，它是可溶于水和有机溶剂的白色固体，可由三氧化二铊和三氟乙酸回流反应制得。[1]
参考文献
- ^ Sibi, Mukund P.; Carpenter, Nancy E. Thallium(III) Trifluoroacetate. Encyclopedia of Reagents for Organic Synthesis. 2001. ISBN 0-471-93623-5. doi:10.1002/047084289X.rt089.
- ^ Clinton R. King; et al. Electrophilic Impact of High-Oxidation State Main-Group Metal and Ligands on Alkane C–H Activation and Functionalization Reactions. Organometallics 2018, 37, 18, 3045–3054. doi:10.1021/acs.organomet.8b00418.
- ^ Clinton R King; et al. Arene C–H Functionalization by p-Block Metal Tl(III) Occurs at the Borderline of C–H Activation and Electron Transfer. Organometallics 2017, 36, 1, 109–113. doi:10.1021/acs.organomet.6b00475.
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