草酸铟
草酸铟 | |
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识别 | |
CAS号 | 5066-15-9 ![]() 735213-71-5 ![]() |
性质 | |
化学式 | In2(C2O4)3 |
摩尔质量 | 493.69 g·mol⁻¹ |
外观 | 白色晶体(六水)[1] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
草酸铟是一种化合物,化学式为In2(C2O4)3。它的水合物可由氯化铟和草酸在水溶液中反应制得。[2]其六水合物在75 °C分解,得到五水合物,在197 °C得到无水物,272 °C生成氧化铟。[1]它在450~465 °C和四氯化碳反应,生成无水氯化铟。[1]它的配阴离子(如[In(C2O4)3]3−)是已知的。[3]
参考文献
[编辑]- ^ 1.0 1.1 1.2 Wiesław Gaweł, Tomasz Kloc, Igor Mucha. Mechanisms of synthesis reaction of pure anhydrous indium(III) chloride. Inorganica Chimica Acta. 2019-09, 495: 118991 [2023-04-06]. doi:10.1016/j.ica.2019.118991 (英语).
- ^ Deichman, E. N. The indium chloride-oxalic acid-water system. Zhurnal Neorganicheskoi Khimii, 1959. 4: 2617-2622.
- ^ Deichman, E. N.; Rodicheva, G. V. Complex sulfates, oxalates, and mixed sulfato-oxalates of indium. Zhurnal Neorganicheskoi Khimii, 1964. 9 (4): 807-812.
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