草酸铟
| 草酸铟 | |
|---|---|
| 识别 | |
| CAS号 | 5066-15-9  735213-71-5
|
| 性质 | |
| 化学式 | In2(C2O4)3 |
| 摩尔质量 | 493.69 g·mol⁻¹ |
| 外观 | 白色晶体（六水）[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
草酸铟是一种化合物，化学式为In2(C2O4)3。它的水合物可由氯化铟和草酸在水溶液中反应制得。[2]其六水合物在75 °C分解，得到五水合物，在197 °C得到无水物，272 °C生成氧化铟。[1]它在450~465 °C和四氯化碳反应，生成无水氯化铟。[1]它的配阴离子（如[In(C2O4)3]3−）是已知的。[3]
参考文献
[编辑]- ^ 1.0 1.1 1.2 Wiesław Gaweł, Tomasz Kloc, Igor Mucha. Mechanisms of synthesis reaction of pure anhydrous indium(III) chloride. Inorganica Chimica Acta. 2019-09, 495: 118991 [2023-04-06]. doi:10.1016/j.ica.2019.118991 （英语）.
- ^ Deichman, E. N. The indium chloride-oxalic acid-water system. Zhurnal Neorganicheskoi Khimii, 1959. 4: 2617-2622.
- ^ Deichman, E. N.; Rodicheva, G. V. Complex sulfates, oxalates, and mixed sulfato-oxalates of indium. Zhurnal Neorganicheskoi Khimii, 1964. 9 (4): 807-812.
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