草酸亚铊
| 草酸亚铊 | ||
|---|---|---|
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| 识别 | ||
| CAS号 | 30737-24-7  75234-59-2
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| 性质 | ||
| 化学式 | C2O4Tl2 | |
| 摩尔质量 | 496.79 g·mol−1 | |
| 外观 | 透明晶体[1] | |
| 密度 | 6.495 g·cm−3[1] | |
| 熔点 | 315—320 °C（588—593 K）（分解）[2] | |
| 溶解性（水） | 可溶[3] | |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | ||
草酸亚铊是一种化合物，化学式为Tl2C2O4。它可由氢氰酸和三氧化二铊在水中于70 °C反应7天得到，[1]或通过碳酸亚铊和草酸在水溶液中反应得到。[4]它可以和亚硝酰氯反应。[5]它受热分解为氧化亚铊和二氧化碳。[4]
参考文献
[编辑]- ^ 1.0 1.1 1.2 Péter Nagy, Andreas Fischer, Julius Glaser, Andrey Ilyukhin, Mikhail Maliarik, Imre Tóth. Solubility, Complex Formation, and Redox Reactions in the Tl 2 O 3 −HCN/CN - −H 2 O System. Crystal Structures of the Cyano Compounds Tl(CN) 3 ·H 2 O, Na[Tl(CN) 4 ]·3H 2 O, K[Tl(CN) 4 ], and Tl I [Tl III (CN) 4 ] and of Tl I 2 C 2 O 4. Inorganic Chemistry. 2005-04-01, 44 (7): 2347–2357 [2022-01-06]. ISSN 0020-1669. doi:10.1021/ic0485918. （原始内容存档于2022-01-06） （英语）.
- ^ Abbott, Royal K., Jr. Organothallium compounds. Iowa State College Journal of Science, 1943. 18: 3-5. CODEN ISCJAF. ISSN 0096-2783.
- ^ Rich, R. Inorganic Reactions in Water. Springer Berlin Heidelberg. 2007: 320 [2022-01-06]. ISBN 978-3-540-73962-3. （原始内容存档于2022-01-06）.
- ^ 4.0 4.1 S.R. Sagi, Karri V. Ramana, M.S.Prasada Rao. Some studies on thallium oxalates. I. Thermal decomposition of ammonium bisoxalatothallate(III). Thermochimica Acta. 1979-08, 31 (3): 285–296 [2022-01-06]. doi:10.1016/0040-6031(79)80043-X. （原始内容存档于2018-06-28） （英语）.
- ^ Dumoulard, Jean P.; Perrot, Roger. Action of nitrosyl chloride on metallic salts（法文）. Comptes Rendus des Seances de l'Academie des Sciences, Serie C: Sciences Chimiques, 1970. 271. 22: 1374-1377. CODEN CHDCAQ. ISSN 0567-6541.
拓展阅读
[编辑]- Gilman, Henry.; Abbott, R. K. Characterization of Sulfonic, Sulfinic, Phosphonic and Some Other Acids as Thallous Salts. Journal of the American Chemical Society (American Chemical Society (ACS)). 1949, 71 (2): 659–660. ISSN 0002-7863. doi:10.1021/ja01170a077.
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