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高锰酸镁

高锰酸镁

Magnesiumion 2 Permanganation

英文名 magnesium permanganate
识别
CAS号 10377-62-5(无水)  checkY
13446-20-3(六水)  checkY
SMILES
 
  • [Mg+2].O=[Mn](=O)(=O)[O-].O=[Mn](=O)(=O)[O-]
性质
化学式 Mg(MnO4)2
溶解性 可溶
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

高锰酸镁是一种无机化合物,化学式为Mg(MnO4)2,可用作氧化剂[1]。它可由氯化镁高锰酸银反应得到,从溶液中可以结晶出六水合物Mg(MnO4)2·6H2O,它略有吸湿性。[2]六水合物受热分解,可以得到无水物。它可以和乙醇丙酮四氢呋喃等有机化合物迅速反应。[3]

参考文献

[编辑]
  1. ^ Saul Wolfe, Christopher F. Ingold. Oxidation of organic compounds by zinc permanganate. Journal of the American Chemical Society. 1983-12, 105 (26): 7755–7757 [2020-06-27]. ISSN 0002-7863. doi:10.1021/ja00364a054. (原始内容存档于2019-10-24) (英语). 
  2. ^ Moles, E.; Crespi, M. Permanganates. III. Anales de la Real Sociedad Espanola de Fisica y Quimica, 1923. 21. 305-316. ISSN: 0365-6675.
  3. ^ Laszlo Kotai, Istvan Gacs, Istvan E. Sajo, Pradeep K. Sharma, Kalyan K. Banerji. ChemInform Abstract: Beliefs and Facts in Permanganate Chemistry - An Overview on the Synthesis and the Reactivity of Simple and Complex Permanganates. ChemInform. 2011-03-29, 42 (13): no–no [2020-06-27]. doi:10.1002/chin.201113233 (英语). 
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高锰酸镁
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