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钛酸镝

钛酸镝
IUPAC名
Dysprosium titanate
识别
CAS号 68993-46-4
SMILES
 
  • [Dy+3].[Dy+3].[Ti+4].[Ti+4].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2]
性质
化学式 Dy2O7Ti2
摩尔质量 532.73 g·mol−1
密度 6.8 g/cm3[1]
结构
晶体结构 烧绿石结构[1]
空间群 Fd3m, cF88, No. 227
晶格常数 a = 1.0136 nm
相关物质
其他阳离子 钛酸钬
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

钛酸镝Dy2Ti2O7)是一种无机化合物,是属于钛酸盐陶瓷,具有烧绿石结构。

钛酸镝与钛酸钬锡酸钬英语holmium stannate一样,是一种自旋冰英语spin ice材料。2009年,已观测到钛酸镝在低温高磁场下拥有类似磁单极子准粒子[2][3]

钛酸镝(Dy2TiO5)自1995年起用作商业核反应堆控制棒材料。[4]

参考文献

[编辑]
  1. ^ 1.0 1.1 Dolgikh V.A., Lavat E.A. Preparation of new oxide nitrides with the pyrochlore structure. Russ. J. Inorg. Chem. 1991, 36: 1389–1392. 
  2. ^ Magnetic Monopoles Detected In A Real Magnet For The First Time. Science Daily. 2009-09-04 [2009-09-04]. (原始内容存档于2018-01-07). 
  3. ^ Morris, D. J. P.; Tennant, D. A.; Grigera, S. A.; Klemke, B.; Castelnovo, C.; Moessner, R.; Czternasty, C.; Meissner, M.; Rule, K. C.; Hoffmann, J.-U.; Kiefer, K.; Gerischer, S.; Slobinsky, D.; Perry, R. S. Dirac Strings and Magnetic Monopoles in Spin Ice Dy2Ti2O7. Science. 2009-09-03, 326 (5951): 411–4. Bibcode:2009Sci...326..411M. PMID 19729617. S2CID 206522398. arXiv:1011.1174可免费查阅. doi:10.1126/science.1178868. 
  4. ^ Risovany, V.D.; Varlashova, E.E.; Suslov, D.N. Dysprosium titanate as an absorber material for control rods. Journal of Nuclear Materials. 2000, 281 (1): 84–89. Bibcode:2000JNuM..281...84R. doi:10.1016/S0022-3115(00)00129-X. 
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钛酸镝
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