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溴化铒

溴化铒
英文名 erbium(III) bromide
识别
CAS号 13536-73-7(无水)  checkY
14890-44-9(六水)  checkY
PubChem 83562
SMILES
 
  • [Br-].[Br-].[Br-].[Er+3]
性质
化学式 ErBr3
外观 玫瑰紫色固体(无水)[1]
粉色固体(六水)[2]
熔点 950 °C(1,220 K)[1]
溶解性 可溶
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

溴化铒是一种无机化合物,化学式为ErBr3。它可由氧化铒溴化铵加热反应制得,[3]其六水合物可从氢溴酸酸化的溴化铒溶液中结晶得到[2]。它和溴化锂在高温反应,得到Li3ErBr6[4]

参考文献

[编辑]
  1. ^ 1.0 1.1 Jantsch, G.; Jawurek, H.; Skalla, N.; Gawalowski, H. Halides of the rare earths. VI. Halides of the terbium and erbium earth groups. Zeitschrift fuer Anorganische und Allgemeine Chemie, 1932. 207. 353-367. ISSN: 0044-2313.
  2. ^ 2.0 2.1 D. Brown, S. Fletcher, D. G. Holah. The preparation and crystallographic properties of certain lanthanide and actinide tribromides and tribromide hexahydrates. Journal of the Chemical Society A: Inorganic, Physical, Theoretical. 1968: 1889 [2020-05-29]. ISSN 0022-4944. doi:10.1039/j19680001889 (英语). 
  3. ^ Gerd Meyer, Siegfried Dötsch, Thomas Staffel. The ammonium-bromide route to anhydrous rare earth bromides MBr3. Journal of the Less Common Metals. 1987-01, 127: 155–160 [2020-05-29]. doi:10.1016/0022-5088(87)90372-9. (原始内容存档于2020-08-25) (英语). 
  4. ^ Andreas Bohnsack, Gert Balzer, Hans-U. Güdel, Mathias S. Wickleder, Gerd Meyer. Ternäre Halogenide vom Typ A3MX6. VII [1]. Die Bromide Li3MBr6 (M=SmLu, Y): Synthese, Kristallstruktur, Ionenbeweglichkeit. Zeitschrift für anorganische und allgemeine Chemie. 1997-09, 623 (9): 1352–1356 [2020-05-29]. ISSN 0044-2313. doi:10.1002/zaac.19976230905 (德语). 
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溴化铒
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