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氟硅酸钠

氟硅酸钠
Unit cell of the compound
IUPAC名
Sodium fluorosilicate
系统名
Sodium hexafluoridosilicate(2–)

[1]

别名 Disodium hexafluorosilicate/sodium fluosilicate/sodium silicofluoride
识别
CAS号 16893-85-9  checkY
PubChem 28127
ChemSpider 26165
SMILES
 
  • [Na+].[Na+].F[Si--](F)(F)(F)(F)F
UN编号 2674
EINECS 240-934-8
RTECS VV8410000
性质
化学式 Na2[SiF6]
摩尔质量 188 g·mol⁻¹
外观 无色固体[2][3]
氣味
密度 2.68 g/cm3[2]
熔点 800 °C(1073 K)(分解[2]
溶解性 0.64 g/100 mL (20 °C)
1.27 g/100 mL (50 °C)
2.45 g/100 mL (100 °C)
溶解性 不溶于乙醇[3]
折光度n
D
1.312
结构[4]
晶体结构 三方
空间群 P321
晶格常数 a = 8.859, c = 5.038
危险性
NFPA 704
0
2
0
 
致死量或浓度:
LDLo最低
70 mg/kg (小鼠口服)
125 mg/kg(兔子口服)[5]
相关物质
其他阳离子 氟硅酸铵

氟硅酸

若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

氟硅酸钠是一种无机化合物化学式为Na2SiF6。分子量188.06。

天然存在

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氟硅酸钠天然存在于稀有矿物 malladrite 中。[6]

性质

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无色无臭无味有吸湿性六方结晶。相对密度2.679。更易溶于酸。遇碱分解为氟化物二氧化硅。不溶于,溶于乙醚。加热至800°C以上时分解为四氟化硅氟化钠[2]有毒。

氟硅酸钠是三方晶系的,晶格参数 a = 885,9 pm,c = 503,8 pm,空间群 P321 (No. 150)。[7]

制备

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可以由氟硅酸氢氧化钠氯化钠碳酸钠反应而成。[3]

它也可以由四氟化硅和氟化钠直接反应而成。

用途

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用作搪瓷和玻璃的助熔剂、乳白剂,镀层添加剂,凝固剂,以及人造冰晶石氟化钠的制取原料。目前市面上含氟牙膏的氟化物也是以氟矽酸鈉為主,也有部分為氟化鈉[8]。此外,部分地區會以氟硅酸鈉為食水加氟

参考文献

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  1. ^ Parent Hydride Names and Substitutive Nomenclature. Nomenclature of Inorganic Chemistry, IUPAC Recommendations 2005 (PDF). RSC Publishing. 2005: 114–135 [2021-05-31]. (原始内容存档 (PDF)于2018-07-09). 
  2. ^ 2.0 2.1 2.2 2.3 Record of Natriumhexafluorosilikat in the GESTIS Substance Database from the IFA英语Institute for Occupational Safety and Health
  3. ^ 3.0 3.1 3.2 NLM Hazardous Substances Data Bank entry for SODIUM SILICOFLUORIDE
  4. ^ Allan Zalkin, J. D. Forrester, David H. Templeton. The Crystal Structure of Sodium Fluorosilicate. Acta Crystallographica. 1964, 17 (11): 1408–1412. doi:10.1107/S0365110X64003516可免费查阅. 
  5. ^ Fluorides (as F). Immediately Dangerous to Life and Health Concentrations (IDLH). National Institute for Occupational Safety and Health (NIOSH). 
  6. ^ 存档副本. [2021-05-31]. (原始内容存档于2021-10-20). 
  7. ^ A. Zalkin, J. D. Forrester, D. H. Templeton: The crystal structure of sodium fluorosilicate, Acta Cryst. (1964) 17, S. 1408–1412; doi:10.1107/S0365110X64003516.
  8. ^ Archived copy. [2009-08-10]. (原始内容存档于2009-03-26). 
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氟硅酸钠
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