氯溴碘甲烷
| 氯溴碘甲烷 | |
|---|---|
| |
| 识别 | |
| CAS号 | 34970-00-8 
|
| 性质 | |
| 化学式 | CHBrClI |
| 摩尔质量 | 255.28 g·mol−1 |
| 密度 | 对光敏感的液体[1] |
| 熔点 | 5 °C（278 K）[2] |
| 沸点 | 88—90 °C（361—363 K）（30 mmHg）[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
氯溴碘甲烷是一种有机化合物，化学式为CHBrClI。它可由溴二碘甲烷的四氯化碳溶液和五氯化锑的二氯甲烷溶液在0 °C反应得到。[1]
它和其它三卤甲烷一样，可以在低温原位脱质子，得到氯溴碘甲基阴离子。如它和苯基氯化汞在叔丁醇钾的存在下反应，可以得到苯基(氯溴碘甲基)汞。[3]
参考文献
- ^ 1.0 1.1 1.2 Dong Bo Li, Siu-Choon Ng, Igor Novak. Novel synthetic approaches to CHBrFI, CHClFI and CHBrClI. Tetrahedron. 2002-07, 58 (29): 5923–5926 [2021-11-02]. doi:10.1016/S0040-4020(02)00532-X （英语）.
- ^ Garino, Mario; Teofili, Ellade. Chlorobromoiodomethane. Gazzetta Chimica Italiana, 1926. 56: 847-852. ISSN 0016-5603
- ^ Charette, A.B.; Aggarwal, V.K.; Aitken, R.A.; Cicchi, S.; Cordero, F. Science of Synthesis: Houben-Weyl Methods of Molecular Transformations Vol. 22: Three Carbon-Heteroatom Bonds: Thio-, Seleno-, and Tellurocarboxylic Acids and Derivatives; Imidic Acids and Derivatives; Ortho Acid Derivatives. Thieme. 2014: 662 [2021-11-02]. ISBN 978-3-13-171961-4. （原始内容存档于2021-11-05）.
| |||||||||||||||||||||||||||
Text is available under the CC BY-SA 4.0 license; additional terms may apply.
Images, videos and audio are available under their respective licenses.
Cover photo is available under {{::mainImage.info.license.name || 'Unknown'}} license.
Cover photo is available under {{::mainImage.info.license.name || 'Unknown'}} license.
Credit:
(see original file).
