二甲基二硝酸锡
| 二甲基二硝酸锡 | |
|---|---|
| |
| 英文名 | Dimethyltin dinitrate Dimethyldinitratostannane |
| 别名 | 二硝酸二甲基锡 |
| 识别 | |
| CAS号 | 5072-81-1 
|
| 性质 | |
| 化学式 | C2H6N2O6Sn |
| 摩尔质量 | 272.79 g·mol−1 |
| 外观 | 极易潮解的白色晶体[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
二甲基二硝酸锡是一种金属有机化合物，化学式为(CH3)2Sn(NO3)2。
制备
二甲基二硝酸锡可由四甲基锡和四氧化二氮反应得到，[1]或由二甲基二氯化锡和硝酸银反应来制备：[2]
- (CH3)2SnCl2 + 2AgNO3 → (CH3)2Sn(NO3)2+ 2 AgCl↓
四甲基锡和过量硝酸亚汞的反应也能得到二甲基二硝酸锡，其它产物还有甲基硝酸汞和金属汞。[3]
性质
参考文献
- ^ 1.0 1.1 1.2 Addison, C. C.; Simpson, W. B.; Walker, A. Dimethyltin dinitrate. Journal of the Chemical Society (Resumed). 1964: 2360. ISSN 0368-1769. doi:10.1039/jr9640002360.
- ^ Gormley, J.J.; Rees, R.G. Preparation of dialkyltin dinitrates. Journal of Organometallic Chemistry. 1966, 5 (3): 291–292. ISSN 0022-328X. doi:10.1016/S0022-328X(00)80369-1.
- ^ Tagliavini, Giuseppe; Cattalini, Lucio; Belluco, Umberto. Research on organic compounds of Sn. I. Reactions between tetramethylin, tetraethylin, and mercuric nitrate. Ricerca Scientifica, Parte 2: Rendiconti, Sezione A: Abiologica, 1962. 2 (3): 286-290. ISSN: 0556-9680.
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