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二十五烷

二十五烷
识别
CAS号 629-99-2  checkY
SMILES
 
  • CCCCCCCCCCCCCCCCCCCCCCCCC
性质
化学式 C25H52
摩尔质量 352.68 g·mol−1
密度 0.799±0.06 g·cm−3(20 °C)
熔点 54 °C(327 K)[1]
沸点 402 °C(675 K)[2]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

二十五烷(英语:Pentacosane)是含有25个碳原子的直链烷烃,化学式为C25H52,外观为无色、透明的蜡状固体。它理论上存在36797588种同分异构体[3]它可由9,17-二十五烷二酮的还原反应[4]1-溴庚烷和1-溴十八烷与金属的反应制得。[5]

参考文献

  1. ^ Koji Nozaki, Rieko Saihara, Kiyoshi Ishikawa, Takashi Yamamoto. Structure of Normal Alkane Evaporated Films: Molecular Orientation. Japanese Journal of Applied Physics. 2007-02-08, 46 (2): 761–769 [2020-11-06]. ISSN 0021-4922. doi:10.1143/JJAP.46.761 (英语). 
  2. ^ Jovan Jovanovic, Dusan Grozdanic. Reliable prediction of heat of vaporization of n-alkanes at 298.15 K. Journal of the Serbian Chemical Society. 2010, 75 (7): 997–1003 [2020-11-06]. ISSN 0352-5139. doi:10.2298/JSC091123067J. (原始内容存档于2020-08-26) (英语). 页面存档备份,存于互联网档案馆
  3. ^ Hans Lohninger. List of Alkanes. VIAS Library - General Chemistry. 2011-05-20 [2020-11-06]. (原始内容存档于2020-05-27). 页面存档备份,存于互联网档案馆
  4. ^ Virginie Chevallier, Mohammed Bouroukba, Dominique Petitjean, Danielle Barth, Paul Dupuis, Michel Dirand. Temperatures and Enthalpies of Solid−Solid and Melting Transitions of the Odd-Numbered n- Alkanes C 21 , C 23 , C 25 , C 27 , and C 29. Journal of Chemical & Engineering Data. 2001-09, 46 (5): 1114–1122 [2020-11-06]. ISSN 0021-9568. doi:10.1021/je0003501 (英语). 
  5. ^ Sun, Guojian. Process for preparation of high purity straight chain odd alkanes. 2009. CN 101397231 A.
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二十五烷
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