乙酰丙酮钒(III)
| 乙酰丙酮钒(III) | |
|---|---|
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| 别名 | 三乙酰丙酮钒 |
| 识别 | |
| CAS号 | 13476-99-8 
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| PubChem | 5377225 |
| ChemSpider | 22199456 |
| SMILES |
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| 性质 | |
| 化学式 | C15H21O6V |
| 摩尔质量 | 348.27 g·mol−1 |
| 外观 | 棕色晶体[1] |
| 密度 | 1.334 g/cm3 |
| 熔点 | 184 °C[2] |
| 危险性 | |
GHS危险性符号  
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| GHS提示词 | 危险 |
| H-术语 | H301, H311, H315, H318, H319, H330, H335 |
| P-术语 | P260, P261, P264, P270, P271, P280, P284, P301+310, P302+352, P304+340, P305+351+338, P310, P312, P320 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
乙酰丙酮钒(III)是一种配位化合物，化学式为V(C5H7O2)3。它可由乙酰丙酮、三异丙醇氧钒和二(三甲基硅基)硫在甲苯中反应制得，[1]或由乙酰丙酮氧钒(IV)在过量乙酰丙酮存在下被锡或锌还原得到。[2]它和氟化钾在甲醇中反应可以得到K3VF6。[3]
参考文献
- ^ 1.0 1.1 M. N. Sokolov, A. V. Virovets, A. V. Rogachev, P. A. Abramov, V. P. Fedin. Reaction of [VO(OPr)3] with hexamethyldisylthiane in the presence of β-diketones. Russian Journal of Coordination Chemistry. 2013-02, 39 (2): 175–180 [2023-04-08]. ISSN 1070-3284. doi:10.1134/S1070328413020085 （英语）.
- ^ 2.0 2.1 Savaridasson Jose Kavitha, Krishnaswamy Panchanatheswaran, Mark R.J. Elsegood, Sophie H. Dale. Mixed ligation to vanadium(III): Synthesis, spectra and structures of bis(acetylacetonato)(o-phenanthroline)vanadium(III) fluoroborate and bis(acetylacetonato)(o-phenanthroline)vanadium(III) perchlorate. Inorganica Chimica Acta. 2006-03, 359 (4): 1314–1320 [2023-04-08]. doi:10.1016/j.ica.2005.12.020. （原始内容存档于2020-02-25） （英语）.
- ^ R. Nagarajan, Neetu Tyagi, Samuel Lofland, K.V. Ramanujachary. Spectroscopic, thermal, magnetic and structural characterization of K3VF6 prepared at room temperature. Polyhedron. 2011-05, 30 (8): 1425–1429 [2023-04-08]. doi:10.1016/j.poly.2011.03.012. （原始内容存档于2018-06-08） （英语）.
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