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一氟化金

一氟化金
识别
CAS号 15194-77-1  checkY
PubChem 21225580
ChemSpider 10605696
SMILES
 
  • [Au]F
性质
化学式 AuF
摩尔质量 215.96 g·mol−1
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

一氟化金是一种无机化合物化学式为AuF。该化合物的固体无法被分离,但通过旋转光谱法[1]质谱法可以观察到它作为气体存在。[2]

一种被NHC配体稳定的一氟化金配合物已得到表征。[3]

参考资料

  1. ^ Evans, Corey J.; Gerry, Michael C. L. Confirmation of the Existence of Gold(I) Fluoride, AuF: Microwave Spectrum and Structure. Journal of the American Chemical Society. 2000, 122 (7): 1560. doi:10.1021/ja9938985. 
  2. ^ Schröder, Detlef; Hrušák, Jan; Tornieporth-Oetting, Inis C.; Klapötke, Thomas M.; Schwarz, Helmut. Neutral Gold(I) Fluoride Does Indeed Exist. Angewandte Chemie International Edition in English. 1994, 33 (2): 212. doi:10.1002/anie.199402121. 
  3. ^ David S. Laitar; Peter Müller; Thomas G. Gray; Joseph P. Sadighi. A Carbene-Stabilized Gold(I) Fluoride: Synthesis and Theory. Organometallics. 2005, 24 (19): 4503–4505. doi:10.1021/om050619f. 
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一氟化金
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