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高氯酸镍

高氯酸镍
别名 高氯酸镍(II)
识别
CAS号 13637-71-3(无水)  checkY
13520-61-1(六水)  checkY
性质
化学式 Ni(ClO4)2
摩尔质量 257.599(无水)
365.695(六水) g·mol⁻¹
外观 黄绿色固体(无水)
青绿色易潮解晶体(六水)
溶解性 259g(六水合物)[1]
相关物质
其他阴离子 高铼酸镍
硝酸镍
其他阳离子 高氯酸亚铁
高氯酸钴
相关化学品 高氯酸
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

高氯酸镍是一种无机化合物化学式为Ni(ClO4)2,是一种强氧化剂

制备

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高氯酸镍可由高氯酸氢氧化镍氯化镍碳酸镍反应得到。[2]

放入6mol/L高氯酸中用50Hz的交流电进行电解,也能得到高氯酸镍。[3]

其无水物由三氟乙酸镍(II)和高氯酸在三氟乙酸溶剂中反应得到。[1]

用途

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高氯酸镍可以用于合成某些含能材料。

参考文献

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  1. ^ 1.0 1.1 谢高阳 等. 无机化学丛书 锰分族 铁系 铂系. 科学出版社, 2011. pp 290. 镍(II)的卤酸盐和高卤酸盐
  2. ^ Daniela Sustac Roman, Nickel (II) perchlorate hexahydrate, Encyclopedia of Reagents for Organic Synthesis, John Wiley & Sons, Ltd, 2001-01-01, ISBN 978-0-470-84289-8 (German) 
  3. ^ 郭花枝,魏建红,张美月. 交流电解制备高氯酸镍[J]. 化学世界, 1991 (12): 531-533
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高氯酸镍
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