磷酸钬
磷酸钬 | ||
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识别 | ||
CAS号 | 14298-39-6(无水) ![]() 16827-78-4(二水) ![]() | |
性质 | ||
化学式 | HoPO4 | |
溶解性(水) | 难溶 | |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
磷酸钬是一种无机化合物,化学式为HoPO4。它的二水合物可由硝酸钬和稀磷酸在水溶液中反应得到。[1]它的无水单晶也可由磷酸二氢铵和氧化钬在氧化铅-五氧化二磷(1:1)熔体中反应,生长得到。[2]它和钼酸钠在高温反应,可以得到Na2Ho(MoO4)(PO4)。[3]
参考文献
[编辑]- ^ J.D. Donaldson, A. Hezel, S.D. Ross. The hydrated phosphates of dysprosium and holmium. Journal of Inorganic and Nuclear Chemistry. 1967-05, 29 (5): 1239–1242 [2022-06-25]. doi:10.1016/0022-1902(67)80364-6 (英语).
- ^ O Gomis, B Lavina, P Rodríguez-Hernández, A Muñoz, R Errandonea, D Errandonea, M Bettinelli. High-pressure structural, elastic, and thermodynamic properties of zircon-type HoPO 4 and TmPO 4. Journal of Physics: Condensed Matter. 2017-03-08, 29 (9): 095401 [2022-06-25]. ISSN 0953-8984. doi:10.1088/1361-648X/aa516a.
- ^ Ryumin, M. A.; Konzissarova, L. N.; Rusakov, D. A.; Bobylev, A. P.; Zhizhin, M. G.; Khoroshilov, A. V.; Gavrichev, K. S.; Danilov, V. P. Synthesis and crystal structure of new complex sodium lanthanide phosphate molybdates Na2MIII(MoO4)(PO4) (MIII = Tb, Dy, Ho, Er, Tm, Lu). Zhurnal Neorganicheskoi Khimii, 2007. 52 (5): 717-724.
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