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碘酸铟

碘酸铟
别名 碘酸铟(III)
识别
CAS号 13510-34-4(无水)  checkY
171434-59-6(三水)  checkY
性质
化学式 In(IO3)3
摩尔质量 639.52 g·mol⁻¹
外观 无色晶体[1]
密度 5.12 g/cm3(α)
5.46 g/cm3(β)[1]
结构
晶体结构 P63(α)或R3(β)[1]
P212121(二水)[2]
P1(三水)[3]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

碘酸铟是一种无机化合物,化学式为In(IO3)3,它可由高碘酸在水溶液中于180 °C反应制得。[4]它存在动力学稳定的偏心三维网络结构的α型和热力学稳定的中心对称的二维网络的β型,α型晶体在365 °C会转化为β型。[1]

参考文献

[编辑]
  1. ^ 1.0 1.1 1.2 1.3 New materials for infrared non-linear optics. Syntheses, structural characterisations, second harmonic generation and optical transparency of M(IO3)3 metallic iodates. Journal of Materials Chemistry. 2007. 17. doi:10.1039/B612677D
  2. ^ Crystal structure of indium triiodate dihydrate, In[IO3]3 · 2H2O. Zeitschrift für Kristallographie - New Crystal Structures, 2014. 221 (3): 247. doi:10.1524/ncrs.2006.0058
  3. ^ Crystal structure of indium triiodate trihydrate, In[IO3]3 · 3H2O. Zeitschrift für Kristallographie - New Crystal Structures, 2014. 221 (3): 249. doi:10.1524/ncrs.2006.0059.
  4. ^ Synthesis and structure of In(IO3)3 and vibrational spectroscopy of M(IO3)3 (M=Al, Ga, In). Journal of Solid State Chemistry. 2006. 179 (12). doi:10.1016/j.jssc.2006.08.026.
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碘酸铟
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