甲酸镉
| 甲酸镉 | ||
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| 识别 | ||
| CAS号 | 4464-23-7 
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| SMILES |
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| 性质 | ||
| 化学式 | Cd(HCOO)2 | |
| 摩尔质量 | 202.45 g·mol⁻¹ | |
| 外观 | 白色固体 | |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | ||
甲酸镉是镉的甲酸盐，化学式为Cd(HCOO)2，它可由碳酸镉和甲酸水溶液反应得到。它在210 °C开始分解，热分解的中间产物是碳酸镉，最终生成氧化镉，惰性气氛中还能检测到金属镉。[1]
它可以和哌啶[2]、联吡啶[3]等有机配体形成配合物。它可用于制备CdS[4]、Cd1−xFexO[5]等含镉材料。
参考文献
[编辑]- ^ Barbara Małecka, Agnieszka Łącz. Thermal decomposition of cadmium formate in inert and oxidative atmosphere. Thermochimica Acta. 2008-12, 479 (1-2): 12–16 [2021-03-17]. doi:10.1016/j.tca.2008.09.003. （原始内容存档于2018-06-26） （英语）.
- ^ Kharitonova, R. I.; Kharitonov, Yu. Ya. Reaction of crystalline cadmium carboxylates with piperidine. Koordinatsionnaya Khimiya, 1975. 1 (7): 916-919. ISSN: 0132-344X.
- ^ Czakis-Sulikowska, D.; Radwanska-Doczekalska, J.; Markiewicz, M. Synthesis and characterization of new dn metal complexes with 4,4'-bipyridine and formates. Polish Journal of Chemistry, 2003. 77 (10). 1255-1261. ISSN: 0137-5083.
- ^ M. Stoev, S. Ruseva, B. Keremidchieva. Preparation of CdS by thermal decomposition of double salts and saturated solutions of the systems Cd(HCOO)2-CS(NH2)2-CH3OH and Cd(CH3COO)2-CS(NH2)2-CH3OH. Monatshefte für Chemie / Chemical Monthly. 1994-11, 125 (11): 1215–1221 [2021-03-17]. ISSN 0026-9247. doi:10.1007/BF00813807 （英语）.
- ^ Vladimir N. Krasil’nikov, Tatyana V. Dyachkova, Alexander P. Tyutyunnik, Olga I. Gyrdasova, Yuliya A. Perevozchikova, Vyacheslav V. Marchenkov, Harald W. Weber. Precursor synthesis and magnetic properties of Cd 1−x Fe x O (0 ⩽ x ⩽ 0.07). Mendeleev Communications. 2017-09, 27 (5): 456–458 [2021-03-17]. doi:10.1016/j.mencom.2017.09.008. （原始内容存档于2018-06-10） （英语）.
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