铜铁试剂
| 铜铁试剂 | |
|---|---|
| |
| 别名 | N-亚硝基苯胲铵 |
| 识别 | |
| CAS号 | 135-20-6 
|
| PubChem | 2724103 |
| ChemSpider | 2006262 |
| SMILES |
|
| InChI |
|
| InChIKey | GDEBSAWXIHEMNF-IKLDFBCSAP |
| 性质 | |
| 化学式 | C6H9N3O2 |
| 摩尔质量 | 155.15 g·mol⁻¹ |
| 熔点 | 150 °C（423 K） |
| 溶解性（水） | 可溶于水 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
铜铁试剂（Cupferron）是N-亚硝基-N-苯基羟胺的铵盐，是金属离子配合物的通用试剂，其化学式为NH4[C6H5N(O)NO]，阴离子用二个氧原子和金属属子进行配位，形成五齿的螯合物。
- C6H5NHOH + C4H9ONO + NH3 → NH4[C6H5N(O)NO] + C4H9OH
参考资料
- D. Van der Helm, L. L. Merritt Jnr, R. Degeilh and C. H. MacGillavry "The crystal structure of iron cupferron Fe(O2N2C6H5)3" Acta Crystallogr. (1965). 18, 355–362
- Merck 13,2649; Beil. 16,IV,891
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