草酸铅
| 草酸铅 | |
|---|---|
_oxalate.svg)
| |
| 英文名 | Lead(II) oxalate |
| 识别 | |
| CAS号 | 814-93-7 
|
| PubChem | 197481 |
| ChemSpider | 55161 |
| SMILES |
|
| InChI |
|
| UN编号 | 2291 |
| 性质 | |
| 化学式 | PbC2O4 |
| 摩尔质量 | 295.219 g·mol⁻¹ |
| 外观 | 白色粉末 |
| 密度 | 5.28 g/cm3 |
| 熔点 | 327.4 °C（601 K） |
| 沸点 | 1740 °C（2013 K） |
| 热力学 | |
| ΔfHm⦵298K | -851.444 kJ/mol |
| S⦵298K | 146.0216 J [1] |
| 危险性 | |
| 欧盟分类 | 6.1 |
GHS危险性符号
| |
| PEL | 0.05 mg/m3, as Pb |
| 相关物质 | |
| 其他阴离子 | 碳酸铅 乙酸铅 |
| 其他阳离子 | 草酸亚锡 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
制备
该化合物有市售品。它可以通过硝酸铅和草酸钠的复分解反应制备：[3]
- Pb2+(aq) + C2O42− → PbC2O4 (s)
溶解性
参考文献
- ^ "Lead(II) Oxalate". Chemistry Reference. http://www.chemistry-reference.com/q_compounds.asp?CAS=814-93-7.
- ^ "Lead Oxalate". American Elements: The World's Manufacturer of Engineered & Advanced Materials. http://www.americanelements.com/pboxl.html （页面存档备份，存于互联网档案馆）.
- ^ Grases, F.; Ruiz, J.; Costa-Bauzá, A. Studies on Lead Oxalate Crystalline Growth. Journal of Colloid and Interface Science. 1993, 155 (2): 265–270. doi:10.1006/jcis.1993.1035.
- ^ Kolthoff, I.M.; Perlich, R. W.; Weiblen, D. The Solubility of lead Sulfate and of Lead Oxalate in Various Media. Journal of Physical Chemistry. 1942, 46 (5): 561. doi:10.1021/j150419a004.
| ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
Text is available under the CC BY-SA 4.0 license; additional terms may apply.
Images, videos and audio are available under their respective licenses.
Cover photo is available under {{::mainImage.info.license.name || 'Unknown'}} license.
Cover photo is available under {{::mainImage.info.license.name || 'Unknown'}} license.
Credit:
(see original file).
