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硝酸铑

硝酸铑

Rhodium-Ion Nitration

别名 硝酸铑(III)
识别
CAS号 10139-58-9(无水)  checkY
13465-43-5(二水)  checkY
性质
化学式 Rh(NO3)3
摩尔质量 288.927(无水)
324.959(二水) g·mol⁻¹
外观 红色或黄色晶体(二水)[1]
溶解性 易溶于水,难溶于乙醇 [1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

硝酸铑是一种无机化合物化学式为Rh(NO3)3,可溶于水,在水溶液中,钌与水分子的氧及硝酸根的氧配位。[2]它可以形成硝酸根配合物[Rh(NO3)​5]​2−[3]它可用于合成含铑材料。[4]

参考资料

  1. ^ 1.0 1.1 《化学化工物性数据手册》(无机卷). 刘光启等 主编. 化学工业出版社. P350. 表8.2.1 硝酸盐的物性总览.ISBN 7-5025-3591-8
  2. ^ R. Caminiti, D. Atzei, P. Cucca, A. Anedda, G. Bongiovanni. Structure of rhodium(III) nitrate aqueous solutions. An investigation by x-ray diffraction and Raman spectroscopy. The Journal of Physical Chemistry. 1986-01, 90 (2): 238–243 [2020-04-23]. ISSN 0022-3654. doi:10.1021/j100274a007. (原始内容存档于2020-09-11) (英语). 
  3. ^ Danila Vasilchenko, Sofia Vorobieva, Iraida Baidina, Dmitry Piryazev, Athanassios Tsipis, Sergey Korenev. Structure and properties of a rhodium(III) pentanitrato complex embracing uni- and bidentate nitrato ligands. Polyhedron. 2018-06, 147: 69–74 [2020-04-23]. doi:10.1016/j.poly.2018.03.017. (原始内容存档于2020-02-09) (英语). 
  4. ^ Aurélie Vicente, Tchirioua Ekou, Gwendoline Lafaye, Catherine Especel, Patrice Marécot, Christopher T. Williams. Influence of the nature of the precursor salts on the properties of Rh–Ge/TiO2 catalysts for citral hydrogenation. Journal of Catalysis. 2010-10-22, 275 (2): 202–210 [2020-04-23]. doi:10.1016/j.jcat.2010.07.015. (原始内容存档于2018-06-03) (英语). 
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硝酸铑
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