硝酸碘
| 硝酸碘 | |
|---|---|
| |
| IUPAC名 Iodo nitrate | |
| 别名 | 次碘酸硝酰酯 |
| 识别 | |
| CAS号 | 14696-81-2 
|
| PubChem | 13406959 |
| ChemSpider | 67165553 |
| SMILES |
|
| 性质 | |
| 化学式 | INO3 |
| 摩尔质量 | 188.91 g·mol−1 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
制备
性质
作为气体，它稍微不稳定，以−3.2×10−2 s−1的速率衰变。[2]人们已经研究了这种物质在大气中的可能形成及其破坏臭氧的能力。可能的反应为：[3]
- IONO2 → IO + NO2
- IONO2 → I + NO3
- I + O3 → IO + O2
参考资料
- ^ 1.0 1.1 Hassner, Alfred. Iodine Nitrate. Encyclopedia of Reagents for Organic Synthesis. 15 April 2001: ri016. ISBN 9780470842898. doi:10.1002/047084289X.ri016.
- ^ 2.0 2.1 Barnes, Ian; Becker, Karl H.; Starcke, Juergen. Fourier-transform IR spectroscopic observation of gaseous nitrosyl iodine, nitryl iodine, and iodine nitrate. The Journal of Physical Chemistry. November 1991, 95 (24): 9736–9740. doi:10.1021/j100177a026.
- ^ Allan, B. J.; Plane, J. M. C. A Study of the Recombination of IO with NO2 and the Stability of INO3: Implications for the Atmospheric Chemistry of Iodine. The Journal of Physical Chemistry A. September 2002, 106 (37): 8634–8641. Bibcode:2002JPCA..106.8634A. doi:10.1021/jp020089q.
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