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氯化银电极

氯化银电极(Silver chloride electrode)是一种参比电极,常用于电化学测量。 出于环境原因,它已广泛取代饱和甘汞电极。 例如,它通常是pH计中的内部参考电极,并且经常用作还原电位测量的参考。 作为后者的一个例子,氯化银电极是最常用的参比电极,用于测试海水环境中的阴极保护腐蚀控制系统。

AgCl 不是由Ag+和Cl-直接结合形成的,而是通过首先由Ag+和Cl-结合形成的可溶物质AgCln + 1–n (0 ≤ n ≤ 3) 转化为固体 AgCl 相而形成[1]

参考文献

  1. ^ Cho, Kang Rae; Kim, Minhye; Kim, Bupmo; Shin, Gahye; Lee, Sangkyu; Kim, Wooyul. Investigation of the AgCl Formation Mechanism on the Ag Wire Surface for the Fabrication of a Marine Low-Frequency-Electric-Field-Detection Ag/AgCl Sensor Electrode. ACS Omega. 2022-07-26, 7 (29). ISSN 2470-1343. PMC 9330149可免费查阅. PMID 35910151. doi:10.1021/acsomega.2c01481 (英语). 
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氯化银电极
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