氯化四吡啶合镍(II)
| 氯化四吡啶合镍(II) | |
|---|---|
| |
| 别名 | 二氯化四吡啶合镍 |
| 识别 | |
| CAS号 | 14076-99-4 
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| 性质 | |
| 化学式 | C10H20Cl2N4Ni |
| 摩尔质量 | 325.89 g·mol−1 |
| 相关物质 | |
| 其他阳离子 | 氯化四吡啶合铁(II) 氯化四吡啶合钴(II) |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
氯化四吡啶合镍(II)是一种配位化合物，化学式为Ni(py)4Cl2，其中py为吡啶。它可由氯化镍和吡啶反应得到。[1]它在140 °C分解，生成Ni(py)2Cl2，继续加热逐渐失去吡啶分子，并最终得到氯化镍。[2]它可用于合成其它镍配合物。[3][4]
参考文献
- ^ David A. Rowley, Russell S. Drago. Crystal field analysis of the spectra of tetragonal nickel(II) pyridine complexes. Inorganic Chemistry. 1967-06, 6 (6): 1092–1095 [2020-05-29]. ISSN 0020-1669. doi:10.1021/ic50052a005 （英语）.
- ^ G. Liptay, K. Burger, é. Mocsári-Fülöp, I. Porubszky. Thermal analysis of metal complexes, III: Investigation of the thermal decomposition of pyridine halide (pseudohalide) mixed complexes and of their decomposition products. Journal of Thermal Analysis. 1970-03, 2 (1): 25–36 [2020-05-29]. ISSN 0022-5215. doi:10.1007/BF01911702 （英语）.
- ^ Van T. Tran, Zi‐Qi Li, Omar Apolinar, Joseph Derosa, Matthew V. Joannou, Steven R. Wisniewski, Martin D. Eastgate, Keary M. Engle. Ni(COD)(DQ): An Air‐Stable 18‐Electron Nickel(0)–Olefin Precatalyst. Angewandte Chemie International Edition. 2020-05-04, 59 (19): 7409–7413 [2020-05-29]. ISSN 1433-7851. doi:10.1002/anie.202000124 （英语）.
- ^ Cristina Esqueda, José C. Alvarado-Monzón, Gabriel Andreu-de-Riquer, J. Alfredo Gutiérrez, Luis M. De León-Rodríguez, Oracio Serrano, José G. Alvarado-Rodríguez, Jorge A. López. Ni(II) and Pd(II) organometallic and coordination complexes with a new tridentate N,N,O-donor ligand. Polyhedron. 2012-06, 40 (1): 11–18 [2020-05-29]. doi:10.1016/j.poly.2012.04.002. （原始内容存档于2020-02-13） （英语）.
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