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壬二酰氯

壬二酰氯
IUPAC名
Nonanedioyl dichloride
识别
CAS号 123-98-8  checkY
PubChem 67165
ChemSpider 60510
SMILES
 
  • C(CCCC(=O)Cl)CCCC(=O)Cl
InChI
 
  • 1S/C9H14Cl2O2/c10-8(12)6-4-2-1-3-5-7-9(11)13/h1-7H2
InChIKey HGEVGSTXQGZPCL-UHFFFAOYSA-N
性质
化学式 C9H14Cl2O2
摩尔质量 225.11 g·mol−1
外观 无色液体
密度 1.144 g/cm3
沸点 138—140 °C(411—413 K)(2 torr)[1]
危险性
GHS危险性符号
《全球化学品统一分类和标签制度》(简称“GHS”)中腐蚀性物质的标签图案
GHS提示词 危险
H-术语 H314
P-术语 P260, P264, P280, P301+330+331, P303+361+353, P304+340, P305+351+338, P310, P321, P363, P405, P501
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

壬二酰氯是一种有机化合物,化学式为(CH2)7(COCl)2,它是无色液体,市售品可能发黄。

它可由壬二酸氯化亚砜草酰氯反应制得。[2][3]三氯化铝催化下,它和1,2-二甲氧基苯英语1,2-Dimethoxybenzene二氯甲烷中反应,可以得到1,9-二(3,4-二甲氧基苯基)-1,9-壬二酮。[4]它和苯甲酰肼德语Benzohydrazid反应,可以得到N,N'-二(苯甲酰基)壬二酰肼。[5]

参考文献

[编辑]
  1. ^ Lagidze, D. R.; Revazishvili, T. N.; Talakvadze, L. I.; Abesadze, I. G.; Lagidze, R. M. Synthesis of demethoxy analogs of melatonin from tryptamine and dicarboxylic acids(俄文). Soobshcheniya Akademii Nauk Gruzinskoi SSR, 1984. 115 (1): 89-92. ISSN 0002-3167.
  2. ^ Anna Zep, Miroslaw Salamonczyk, Nataša Vaupotič, Damian Pociecha, Ewa Gorecka. Physical gels made of liquid crystalline B4 phase. Chemical Communications. 2013, 49 (30): 3119 [2022-08-26]. ISSN 1359-7345. doi:10.1039/c3cc41225c (英语). 
  3. ^ M. Praveen Kumar, Jakub Karcz, Przemyslaw Kula, Surajit Dhara. Dynamics of a sheared twist-bend nematic liquid crystal. Physical Review Materials. 2021-11-29, 5 (11) [2022-08-26]. ISSN 2475-9953. doi:10.1103/PhysRevMaterials.5.115605 (英语). 
  4. ^ Ziad Omran, Alexandre Specht. Synthesis and photochemical properties of photo-cleavable crosslinkers. Tetrahedron Letters. 2009-05, 50 (20): 2434–2436 [2022-08-26]. doi:10.1016/j.tetlet.2009.03.009. (原始内容存档于2018-06-10) (英语). 
  5. ^ Yanhua Cai, Shifeng Yan, Yinqing Fan, Zhuyi Yu, Xuesi Chen, Jingbo Yin. The nucleation effect of N,N′-bis(benzoyl) alkyl diacid dihydrazides on crystallization of biodegradable poly(l-lactic acid). Iranian Polymer Journal. 2012-07, 21 (7): 435–444 [2022-08-26]. ISSN 1026-1265. doi:10.1007/s13726-012-0046-x (英语). 
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壬二酰氯
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