亚铁氰酸铯
| 亚铁氰酸铯 | |
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| 别名 | 亚铁氰化铯 六氰合铁(II)酸铯 |
| 识别 | |
| CAS号 | 15614-54-7 
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| 性质 | |
| 化学式 | Cs4[Fe(CN)6] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
亚铁氰酸铯是一种配位化合物，化学式为Cs4[Fe(CN)6]。它可由亚铁氰酸（通过钾盐经IR-120阳离子交换树脂交换得到）和氢氧化铯（或碳酸铯[1]）反应得到。[2]Cs4[Fe(CN)4]在液氨中被氰化铵氧化，也能得到Cs4[Fe(CN)6]。[3]它在590 °C开始分解，生成氰化亚铁和氰化铯。[4]
参考文献
[编辑]- ^ Komissarova, P. D.; Krestovnikova, S. A. Cesium ferrocyanide. Metody Polucheniya Khimicheskikh Reaktivov i Preparatov, 1967. 16. 99-100. ISSN: 0539-5143
- ^ Basinski, Antoni; Szablewski, Lech. A new method of preparation of alkali ferro- and ferricyanides. Chemia Analityczna (Warsaw, Poland), 1966. 11 (1): 199-200. ISSN: 0009-2223.
- ^ Elaine S. Dodsworth, Peter J. O'Grady, David Nicholls, David Roberts. The reactions of iron(III) bromide and iron(II) thiocyanate with ammonia and their reductions with alkali metals in liquid-ammonia solutions of alkali metal cyanides. Polyhedron. 1987-01, 6 (6): 1191–1195 [2020-12-15]. doi:10.1016/S0277-5387(00)80868-2 （英语）.
- ^ Seifer, G. B. Thermal decomposition of ferrocyanides of alkali metals. Zhurnal Neorganicheskoi Khimii, 1962. 7: 1242-1246. ISSN: 0044-457X.
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