氯化镉铯
| 氯化镉铯 | |
|---|---|
| IUPAC名 Caesium cadmium chloride | |
| 识别 | |
| CAS号 | 13845-08-4 
|
| 性质 | |
| 化学式 | CsCdCl3 |
| 摩尔质量 | 351.675 g/mol g·mol⁻¹ |
| 外观 | 白色或无色固体 |
| 结构 | |
| 晶体结构 | 六方 |
| 空间群 | P63/mmc |
| 晶格常数 | a = 7.403, c = 18.406 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
氯化镉铯（CsCdCl3）是一种合成晶体材料。它属于AMX3组（A = 碱金属，M = 二价金属，X = 卤素离子）。它在六方空间群P63/mmc结晶，晶胞长度a = 7.403 Å而c = 18.406 Å，其中一个镉离子具有D3d对称，另一个具有C3v对称。[1]
它由含有等化学计量比的氯化铯和氯化镉溶液的盐酸溶液中结晶得到。[2]
参考文献
[编辑]- ^ Chang, Jin Rong.; McPherson, Gary L.; Atwood, Jerry L. Electron paramagnetic resonance spectra of vanadium(II) and nickel(II) doped into crystals of cesium cadmium chloride and a redetermination of the structure of cesium cadmium chloride. Inorganic Chemistry. December 1975, 14 (12): 3079–3085. doi:10.1021/ic50154a044.
- ^ Electron paramagnetic spectrum of manganese(II)-manganese(II) pairs in single crystals of cesium cadmium chloride. Electronic structure of the nonachlorodimanganate(5-) dimer Gary L. McPherson, and Jin Rong Chang, Inorg. Chem., 1976, 15 (5), 1018-1022. doi:10.1021/ic50159a006
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